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Low-density three-dimensional foam using self-reinforced hybrid two-dimensional atomic layers

Author

Listed:
  • Soumya Vinod

    (Rice University)

  • Chandra Sekhar Tiwary

    (Rice University
    Materials Engineering, Indian Institute of Science)

  • Pedro Alves da Silva Autreto

    (Rice University
    Instituto de Física 'Gleb Wataghin', Universidade Estadual de Campinas)

  • Jaime Taha-Tijerina

    (Rice University)

  • Sehmus Ozden

    (Rice University)

  • Alin Cristian Chipara

    (Rice University)

  • Robert Vajtai

    (Rice University)

  • Douglas S. Galvao

    (Instituto de Física 'Gleb Wataghin', Universidade Estadual de Campinas)

  • Tharangattu N. Narayanan

    (CSIR-Central Electrochemical Research Institute (CSIR-CECRI))

  • Pulickel M. Ajayan

    (Rice University)

Abstract

Low-density nanostructured foams are often limited in applications due to their low mechanical and thermal stabilities. Here we report an approach of building the structural units of three-dimensional (3D) foams using hybrid two-dimensional (2D) atomic layers made of stacked graphene oxide layers reinforced with conformal hexagonal boron nitride (h-BN) platelets. The ultra-low density (1/400 times density of graphite) 3D porous structures are scalably synthesized using solution processing method. A layered 3D foam structure forms due to presence of h-BN and significant improvements in the mechanical properties are observed for the hybrid foam structures, over a range of temperatures, compared with pristine graphene oxide or reduced graphene oxide foams. It is found that domains of h-BN layers on the graphene oxide framework help to reinforce the 2D structural units, providing the observed improvement in mechanical integrity of the 3D foam structure.

Suggested Citation

  • Soumya Vinod & Chandra Sekhar Tiwary & Pedro Alves da Silva Autreto & Jaime Taha-Tijerina & Sehmus Ozden & Alin Cristian Chipara & Robert Vajtai & Douglas S. Galvao & Tharangattu N. Narayanan & Pulick, 2014. "Low-density three-dimensional foam using self-reinforced hybrid two-dimensional atomic layers," Nature Communications, Nature, vol. 5(1), pages 1-9, December.
  • Handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms5541
    DOI: 10.1038/ncomms5541
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