Author
Listed:
- Soumya Vinod
(Rice University)
- Chandra Sekhar Tiwary
(Rice University
Materials Engineering, Indian Institute of Science)
- Pedro Alves da Silva Autreto
(Rice University
Instituto de Física 'Gleb Wataghin', Universidade Estadual de Campinas)
- Jaime Taha-Tijerina
(Rice University)
- Sehmus Ozden
(Rice University)
- Alin Cristian Chipara
(Rice University)
- Robert Vajtai
(Rice University)
- Douglas S. Galvao
(Instituto de Física 'Gleb Wataghin', Universidade Estadual de Campinas)
- Tharangattu N. Narayanan
(CSIR-Central Electrochemical Research Institute (CSIR-CECRI))
- Pulickel M. Ajayan
(Rice University)
Abstract
Low-density nanostructured foams are often limited in applications due to their low mechanical and thermal stabilities. Here we report an approach of building the structural units of three-dimensional (3D) foams using hybrid two-dimensional (2D) atomic layers made of stacked graphene oxide layers reinforced with conformal hexagonal boron nitride (h-BN) platelets. The ultra-low density (1/400 times density of graphite) 3D porous structures are scalably synthesized using solution processing method. A layered 3D foam structure forms due to presence of h-BN and significant improvements in the mechanical properties are observed for the hybrid foam structures, over a range of temperatures, compared with pristine graphene oxide or reduced graphene oxide foams. It is found that domains of h-BN layers on the graphene oxide framework help to reinforce the 2D structural units, providing the observed improvement in mechanical integrity of the 3D foam structure.
Suggested Citation
Soumya Vinod & Chandra Sekhar Tiwary & Pedro Alves da Silva Autreto & Jaime Taha-Tijerina & Sehmus Ozden & Alin Cristian Chipara & Robert Vajtai & Douglas S. Galvao & Tharangattu N. Narayanan & Pulick, 2014.
"Low-density three-dimensional foam using self-reinforced hybrid two-dimensional atomic layers,"
Nature Communications, Nature, vol. 5(1), pages 1-9, December.
Handle:
RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms5541
DOI: 10.1038/ncomms5541
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