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Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics

Author

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  • Liang Kou

    (MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Zhejiang University)

  • Tieqi Huang

    (MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Zhejiang University)

  • Bingna Zheng

    (MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Zhejiang University)

  • Yi Han

    (MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Zhejiang University)

  • Xiaoli Zhao

    (MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Zhejiang University)

  • Karthikeyan Gopalsamy

    (MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Zhejiang University)

  • Haiyan Sun

    (MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Zhejiang University)

  • Chao Gao

    (MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Zhejiang University)

Abstract

Yarn supercapacitors have great potential in future portable and wearable electronics because of their tiny volume, flexibility and weavability. However, low-energy density limits their development in the area of wearable high-energy density devices. How to enhance their energy densities while retaining their high-power densities is a critical challenge for yarn supercapacitor development. Here we propose a coaxial wet-spinning assembly approach to continuously spin polyelectrolyte-wrapped graphene/carbon nanotube core-sheath fibres, which are used directly as safe electrodes to assembly two-ply yarn supercapacitors. The yarn supercapacitors using liquid and solid electrolytes show ultra-high capacitances of 269 and 177 mF cm−2 and energy densities of 5.91 and 3.84 μWh cm−2, respectively. A cloth supercapacitor superior to commercial capacitor is further interwoven from two individual 40-cm-long coaxial fibres. The combination of scalable coaxial wet-spinning technology and excellent performance of yarn supercapacitors paves the way to wearable and safe electronics.

Suggested Citation

  • Liang Kou & Tieqi Huang & Bingna Zheng & Yi Han & Xiaoli Zhao & Karthikeyan Gopalsamy & Haiyan Sun & Chao Gao, 2014. "Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics," Nature Communications, Nature, vol. 5(1), pages 1-10, September.
  • Handle: RePEc:nat:natcom:v:5:y:2014:i:1:d:10.1038_ncomms4754
    DOI: 10.1038/ncomms4754
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    Cited by:

    1. Bo Fang & Jianmin Yan & Dan Chang & Jinli Piao & Kit Ming Ma & Qiao Gu & Ping Gao & Yang Chai & Xiaoming Tao, 2022. "Scalable production of ultrafine polyaniline fibres for tactile organic electrochemical transistors," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

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