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Coastal aquifers key contributors to ocean chemistry through solute fluxes

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  • Yael Kiro

    (Weizmann Institute of Science)

Abstract

Understanding the ocean’s chemical composition is key to assessing the carbon cycle and its climate impact, especially through its control on calcium carbonate saturation and preservation. While rivers and hydrothermal systems are recognized contributors to ocean chemistry, the role of coastal aquifers has been underestimated. This study shows that long-term submarine groundwater discharge (SGD) is a major source of solute fluxes to the ocean, especially of calcium and alkalinity, while removing sodium and potassium. Through analysis of elemental and isotopic ocean budgets, we find that fluxes from long-term SGD rival those from rivers in magnitude. These fluxes influence the residence times of major elements and significantly affect the global carbon budget. Moreover, they are dynamically linked to sea-level changes: falling sea levels enhance SGD-driven solute inputs, whereas rising sea levels suppress them. These patterns suggest that SGD fluxes may regulate long-term climate trends, including rates of global cooling or warming.

Suggested Citation

  • Yael Kiro, 2025. "Coastal aquifers key contributors to ocean chemistry through solute fluxes," Nature Communications, Nature, vol. 16(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-62411-8
    DOI: 10.1038/s41467-025-62411-8
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    References listed on IDEAS

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    1. Elco Luijendijk & Tom Gleeson & Nils Moosdorf, 2020. "Fresh groundwater discharge insignificant for the world’s oceans but important for coastal ecosystems," Nature Communications, Nature, vol. 11(1), pages 1-12, December.
    2. Holly A. Michael & Ann E. Mulligan & Charles F. Harvey, 2005. "Seasonal oscillations in water exchange between aquifers and the coastal ocean," Nature, Nature, vol. 436(7054), pages 1145-1148, August.
    3. Richard D. Berg & Evan A. Solomon & Fang-Zhen Teng, 2019. "The role of marine sediment diagenesis in the modern oceanic magnesium cycle," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    4. Netta Shalev & Tomaso R. R. Bontognali & C. Geoffrey Wheat & Derek Vance, 2019. "New isotope constraints on the Mg oceanic budget point to cryptic modern dolomite formation," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
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