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Heterophase fcc-2H-fcc gold nanorods

Author

Listed:
  • Zhanxi Fan

    (City University of Hong Kong
    City University of Hong Kong
    Nanyang Technological University
    Lawrence Berkeley National Laboratory)

  • Michel Bosman

    (National University of Singapore
    Agency for Science, Technology, and Research (A*STAR))

  • Zhiqi Huang

    (City University of Hong Kong)

  • Ye Chen

    (Nanyang Technological University)

  • Chongyi Ling

    (City University of Hong Kong
    Southeast University)

  • Lin Wu

    (Agency for Science, Technology, and Research (A*STAR))

  • Yuriy A. Akimov

    (Agency for Science, Technology, and Research (A*STAR))

  • Robert Laskowski

    (Agency for Science, Technology, and Research (A*STAR))

  • Bo Chen

    (Nanyang Technological University)

  • Peter Ercius

    (Lawrence Berkeley National Laboratory)

  • Jian Zhang

    (Nanyang Technological University)

  • Xiaoying Qi

    (Agency for Science, Technology, and Research (A*STAR))

  • Min Hao Goh

    (Agency for Science, Technology, and Research (A*STAR))

  • Yiyao Ge

    (Nanyang Technological University)

  • Zhicheng Zhang

    (Nanyang Technological University)

  • Wenxin Niu

    (Nanyang Technological University)

  • Jinlan Wang

    (Southeast University)

  • Haimei Zheng

    (Lawrence Berkeley National Laboratory
    University of California)

  • Hua Zhang

    (City University of Hong Kong
    City University of Hong Kong)

Abstract

The crystal phase-based heterostructures of noble metal nanomaterials are of great research interest for various applications, such as plasmonics and catalysis. However, the synthesis of unusual crystal phases of noble metals still remains a great challenge, making the construction of heterophase noble metal nanostructures difficult. Here, we report a one-pot wet-chemical synthesis of well-defined heterophase fcc-2H-fcc gold nanorods (fcc: face-centred cubic; 2H: hexagonal close-packed with stacking sequence of “AB”) at mild conditions. Single particle-level experiments and theoretical investigations reveal that the heterophase gold nanorods demonstrate a distinct optical property compared to that of the conventional fcc gold nanorods. Moreover, the heterophase gold nanorods possess superior electrocatalytic activity for the carbon dioxide reduction reaction over their fcc counterparts under ambient conditions. First-principles calculations suggest that the boosted catalytic performance stems from the energetically favourable adsorption of reaction intermediates, endowed by the unique heterophase characteristic of gold nanorods.

Suggested Citation

  • Zhanxi Fan & Michel Bosman & Zhiqi Huang & Ye Chen & Chongyi Ling & Lin Wu & Yuriy A. Akimov & Robert Laskowski & Bo Chen & Peter Ercius & Jian Zhang & Xiaoying Qi & Min Hao Goh & Yiyao Ge & Zhicheng , 2020. "Heterophase fcc-2H-fcc gold nanorods," Nature Communications, Nature, vol. 11(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-020-17068-w
    DOI: 10.1038/s41467-020-17068-w
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    Cited by:

    1. Yangbo Ma & Liang Guo & Liang Chang & Weihua Guo & Tao Zhou & Fengkun Hao & Wenda Su & Jingwen Zhou & Guozhi Wang & Mingzheng Shao & Jihan Yu & Jinwen Yin & Yunhao Wang & Fu Liu & An Zhang & Kun Qian , 2025. "Unconventional phase metal heteronanostructures with tunable exposed interface for efficient tandem nitrate electroreduction to ammonia," Nature Communications, Nature, vol. 16(1), pages 1-14, December.
    2. Kai Liu & Hao Yang & Yilan Jiang & Zhaojun Liu & Shumeng Zhang & Zhixue Zhang & Zhun Qiao & Yiming Lu & Tao Cheng & Osamu Terasaki & Qing Zhang & Chuanbo Gao, 2023. "Coherent hexagonal platinum skin on nickel nanocrystals for enhanced hydrogen evolution activity," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    3. Geng Wu & Xiao Han & Jinyan Cai & Peiqun Yin & Peixin Cui & Xusheng Zheng & Hai Li & Cai Chen & Gongming Wang & Xun Hong, 2022. "In-plane strain engineering in ultrathin noble metal nanosheets boosts the intrinsic electrocatalytic hydrogen evolution activity," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

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