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Effect of Cationic Photoinitiator on the Polymerization Kinetics of Vinyl Ether Monomers

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  • Tran Nhung Hien Phuong
  • Pham Thi Kim Hue
  • Luu Bach Hiep
  • Hoang Thi Kieu Nguyen

Abstract

In this study, the performance of a new triarylsulfonium photoinitiators in the initiation of cationic polymerization of vinyl monomers was investigated by infrared spectroscopy (IR). The photoinitiator exhibit absorption characteristics compatible with the emission characteristics of medium pressure mercury lamps, which are the main sources of UV light in the industry. The experimental results indicate that the photoinitiator is most effective at a concentration of 1%. At the investigated conditions, the maximal conversion degree is 77.8% and the polymerization rate is 0.56 s-1. The curing process is even faster than the corresponding free-radical photopolymerization of acrylic monomers

Suggested Citation

  • Tran Nhung Hien Phuong & Pham Thi Kim Hue & Luu Bach Hiep & Hoang Thi Kieu Nguyen, 2020. "Effect of Cationic Photoinitiator on the Polymerization Kinetics of Vinyl Ether Monomers," International Journal of Scientific Research in Science, Engineering and Technology, International Journal of Scientific Research in Science, Engineering and Technology, vol. 7(6), pages 48-53, December.
  • Handle: RePEc:ijs:ijsrse:v7:y2020:i6:id:hijsrset20767
    DOI: 10.32628/IJSRSET20767
    Note: Article URL: https://ijsrset.com/IJSRSET20767
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