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On a numerical model for diffusion-controlled growth and dissolution of spherical precipitates

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  • R. Van Keer
  • J. Kacur

Abstract

This paper deals with a numerical model for the kinetics of some diffusion-limited phase transformations. For the growth and dissolution processes in 3D we consider a single spherical precipitate at a constant and uniform concentration, centered in a finite spherical cell of a matrix, at the boundary of which there is no mass transfer, see also Asthana and Pabi [1] and Caers [2]. The governing equations are the diffusion equation (2nd Fick's law) for the concentration of dissolved element in the matrix, with a known value at the precipitate-matrix interface, and the flux balans (1st Fick's law) at this interface. The numerical method, outlined for this free boundary value problem (FBP), is based upon a fixed domain transformation and a suitably adapted nonconforming finite element technique for the space discretization. The algorithm can be implemented on a PC. By numerous experiments the method is shown to give accurate numerical results.

Suggested Citation

  • R. Van Keer & J. Kacur, 1998. "On a numerical model for diffusion-controlled growth and dissolution of spherical precipitates," Mathematical Problems in Engineering, Hindawi, vol. 4, pages 1-19, January.
  • Handle: RePEc:hin:jnlmpe:267240
    DOI: 10.1155/S1024123X98000751
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