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Chemically Modified Cyclodextrins: An Attractive Class of Supramolecular Hosts for the Development of Aqueous Biphasic Catalytic Processes

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  • Hervé Bricout

    () (Univ Lille Nord de France, F-59000 Lille, France
    UArtois, UCCS, Faculté des Sciences Jean Perrin, Rue Jean Souvraz, SP 18-62307 Lens Cedex F-62300 Lens, France
    CNRS, UMR 8181, F-59650 Villeneuve d’Ascq, France)

  • Frédéric Hapiot

    () (Univ Lille Nord de France, F-59000 Lille, France
    UArtois, UCCS, Faculté des Sciences Jean Perrin, Rue Jean Souvraz, SP 18-62307 Lens Cedex F-62300 Lens, France
    CNRS, UMR 8181, F-59650 Villeneuve d’Ascq, France)

  • Anne Ponchel

    () (Univ Lille Nord de France, F-59000 Lille, France
    UArtois, UCCS, Faculté des Sciences Jean Perrin, Rue Jean Souvraz, SP 18-62307 Lens Cedex F-62300 Lens, France
    CNRS, UMR 8181, F-59650 Villeneuve d’Ascq, France)

  • Sébastien Tilloy

    () (Univ Lille Nord de France, F-59000 Lille, France
    UArtois, UCCS, Faculté des Sciences Jean Perrin, Rue Jean Souvraz, SP 18-62307 Lens Cedex F-62300 Lens, France
    CNRS, UMR 8181, F-59650 Villeneuve d’Ascq, France)

  • Eric Monflier

    () (Univ Lille Nord de France, F-59000 Lille, France
    UArtois, UCCS, Faculté des Sciences Jean Perrin, Rue Jean Souvraz, SP 18-62307 Lens Cedex F-62300 Lens, France
    CNRS, UMR 8181, F-59650 Villeneuve d’Ascq, France)

Abstract

During these last years, cyclodextrins have contributed greatly to the development of catalytic processes in water. These cyclic oligosaccharides composed of 6(α), 7(β) or 8(γ) glucopyranose units improve the mass transfer in aqueous-organic two-phase systems and are useful compounds to design new catalysts. Thus, chemically modified cyclodextrins can be used to: (i) increase significantly the rate and selectivity of reactions catalyzed by water-soluble organometallic complexes, (ii) design new water-soluble ligands for aqueous organometallic catalysis, (iii) stabilize catalytically active noble metal nanoparticles in water and (iv) favour the dispersion and activation of the palladium on charcoal in water.

Suggested Citation

  • Hervé Bricout & Frédéric Hapiot & Anne Ponchel & Sébastien Tilloy & Eric Monflier, 2009. "Chemically Modified Cyclodextrins: An Attractive Class of Supramolecular Hosts for the Development of Aqueous Biphasic Catalytic Processes," Sustainability, MDPI, Open Access Journal, vol. 1(4), pages 1-22, October.
  • Handle: RePEc:gam:jsusta:v:1:y:2009:i:4:p:924-945:d:6028
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    More about this item

    Keywords

    cyclodextrin; aqueous organometallic catalysis; nanoparticles; palladium on charcoal;

    JEL classification:

    • Q - Agricultural and Natural Resource Economics; Environmental and Ecological Economics
    • Q0 - Agricultural and Natural Resource Economics; Environmental and Ecological Economics - - General
    • Q2 - Agricultural and Natural Resource Economics; Environmental and Ecological Economics - - Renewable Resources and Conservation
    • Q3 - Agricultural and Natural Resource Economics; Environmental and Ecological Economics - - Nonrenewable Resources and Conservation
    • Q5 - Agricultural and Natural Resource Economics; Environmental and Ecological Economics - - Environmental Economics
    • Q56 - Agricultural and Natural Resource Economics; Environmental and Ecological Economics - - Environmental Economics - - - Environment and Development; Environment and Trade; Sustainability; Environmental Accounts and Accounting; Environmental Equity; Population Growth
    • O13 - Economic Development, Innovation, Technological Change, and Growth - - Economic Development - - - Agriculture; Natural Resources; Environment; Other Primary Products

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