On the Way to Improve the Environmental Benignity of Chemical Processes: Novel Catalysts for a Polymerization Process
An example for a process that can, in principle, be improved by the application of a catalyst is the synthesis of poly(2-methyl-propene)s (â€œpolyisobutenesâ€ ), which are important for numerous industrial applications. Each year several 100,000 t are produced. The production of low-molecular weight polyisobutenes by means of cationic initiation by an excess of Lewis acids is well established. Typically, these initiators require the usage of solvents like chloroform, dichloromethane and ethylene and temperatures far below 0 Â°C (â€“100 Â°C in the case of ethylene as solvent). Solvent stabilized transition metal complexes with weakly coordinating counter anions overcome these drawbacks and thus are not only more efficient, but also more environmentally benign: they can be applied at ambient temperature and in non chlorinated solvents at low concentrations.
When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:1:y:2009:i:1:p:35-42:d:4304. See general information about how to correct material in RePEc.
For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: (XML Conversion Team)
If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.
If references are entirely missing, you can add them using this form.
If the full references list an item that is present in RePEc, but the system did not link to it, you can help with this form.
If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your profile, as there may be some citations waiting for confirmation.
Please note that corrections may take a couple of weeks to filter through the various RePEc services.