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Ternary Co-Pyrolysis of Soma Lignite, Sugar Beet Pulp, and Hazelnut Husk: Synergistic Effects, Pseudo-Component Behavior, and Optimal Blend Design

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  • Kazım Eşber Özbaş

    (Industrial Engineering Department, Faculty of Engineering, Aksaray University, Aksaray 68100, Türkiye)

Abstract

This study investigates the ternary co-pyrolysis behavior of Soma lignite (SL), sugar beet pulp (SBP), and hazelnut husk (HH) at four blending ratios (80:10:10, 60:20:20, 40:30:30, and 20:40:40 wt.%) using thermogravimetric analysis under a nitrogen atmosphere. Synergistic interactions were quantified through mass-based ( Δ W ) and rate-based ( Ψ ) deviation indices, and the contributions of individual pseudo-components were resolved by Gaussian deconvolution of DTG curves. Among the blends investigated, the 40:30:30 (SL:SBP:HH) composition exhibited the most consistent and intense synergistic effect across all temperature zones, with the strongest promotion concentrated in the high-temperature region associated with CaCO 3 mineral decomposition. Deconvolution analysis revealed that increasing the biomass fraction systematically shifted coal-related pseudo-component peaks to lower temperatures and enhanced the hemicellulose/pectin contribution, confirming that biomass-derived volatiles accelerate lignite devolatilization. These findings demonstrate that ternary co-pyrolysis of low-rank coal with two complementary agricultural by-products is a viable and sustainable strategy to enhance pyrolysis performance, valorize agro-industrial waste, and reduce the environmental footprint of lignite utilization, providing fundamental thermochemical data for the design of integrated lignite–biomass co-processing systems.

Suggested Citation

  • Kazım Eşber Özbaş, 2026. "Ternary Co-Pyrolysis of Soma Lignite, Sugar Beet Pulp, and Hazelnut Husk: Synergistic Effects, Pseudo-Component Behavior, and Optimal Blend Design," Sustainability, MDPI, vol. 18(8), pages 1-26, April.
  • Handle: RePEc:gam:jsusta:v:18:y:2026:i:8:p:3952-:d:1921392
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