Potassium Fertilization as a Steering Tool for Sustainable Valorization of Cereal Straw in Circular Bioeconomy Value Chains

Potassium (K) fertilization plays a key role in regulating stem morphology, particularly stem diameter, yet the influence of different K fertilizer formulations on stem structure and tensile strength remains insufficiently understood. Cereal straw is a key lignocellulosic by-product with growing importance in the circular bioeconomy. Thus, the aim of this study was to determine the links between potassium nutrition, stem structure, and mechanical behavior for four cereal species: wheat, barley, rye, and oats. There were three potassium fertilization levels (0, 60, and 120 kg K ha −1 ) conducted in a field experiment in eastern Croatia (2021/2022). At maturity, stem morphology, macroelements (Ca, K, P, C, N), acid detergent fiber (ADF), neutral detergent fiber (NDF), and uniaxial tensile properties (maximum force, tensile strength, Young’s modulus) were determined. Cereal species was the dominant source of variation ( p < 0.0001) for all traits, whereas the main effect of K was generally weak and significant only for stem diameter at the midpoint and N concentration, although K × species interactions were frequent. Oats and rye showed the most vigorous biomass production, whereas wheat exhibited by far the highest tensile strength (about 120 MPa) and stiffness (6.23 GPa), together with the highest ADF, while barley had the greatest NDF. Oat stems had the lowest ADF and NDF, indicating less lignified, more digestible tissues but mechanically weaker straw. Mechanical traits were tightly and positively correlated with ADF, NDF, and CN ratio, whereas P showed weak or negative associations with plant size and strength. Therefore, for targeted straw valorization, cereal species selection is paramount, with potassium fertilization playing a secondary, species-dependent role.