Integrated Assessment of Energy Recovery Strategies and Sustainable Management for Municipal Solid Waste

High-value components in the organic fraction of both municipal and industrial waste are still underused. In fact, there are two components in organic matter with high energy and emission value: carbohydrates (up to 46%) and fats (3.9–25%). The technological potential of using an integrated sequential biorefinery route, including lipid extraction for HVO/SAF, carbohydrate fermentation for bioethanol, and pyrolysis for renewable hydrogen generation, is not fully exploited. The objective of this work is to propose an approach based on a systematic six-step engineering methodology to determine the feasibility of its recovery. This integrated strategy achieves an attractive economic performance, with payback periods between 1.97 and 3.00 years, significantly outperforming traditional waste-to-energy models such as anaerobic digestion or composting. While current green hydrogen production costs range from USD 4.28 to USD 6.86, our model positions urban waste as a competitive feedstock for energy transition, achieving a selling price of 4.84 EUR/kg at midpoint values. For the remaining organic matter, a definitive thermal barrier for the 100% removal of microplastics is proposed, to prevent them from reaching agricultural soils. At the same time, efficient waste characterization, aligned with the European RED III directive, will allow the identification of high-value products and the application of the best available techniques for their extraction and use.