Assessment of Marine Water Quality Using Integrated Indices and Machine Learning Framework in the Arabian Gulf Region

This study presents an integrated computational framework for quantifying industrial impacts on marine ecosystems through the combined assessment of multiple environmental quality indices. The Aquatic Water Quality Index (AWQI) and four diagnostic pollution indices, namely the Heavy Metal Pollution Index (HPI), Metal Index (MI), Degree of Contamination (C d ), and Pollution Index (PI), were applied across 23 offshore sites in Mesaieed Industrial City, Qatar, to establish a high-resolution baseline for evaluating the effects of industrial effluents and brine discharge. Multivariate statistical analyses, including Principal Component Analysis (PCA) and Cluster Analysis (CA), identified Cr, Pb, Mn, Ni, and Zn as the principal drivers of water quality variability, effectively distinguishing anthropogenic influences from natural background conditions. To enable rapid and automated marine environmental assessment, three machine learning models—Artificial Neural Networks (ANN), Random Forest (RF), and Decision Trees (DT)—were developed and evaluated for predicting the investigated indices. Model performance was assessed through rigorous training–testing validation and the Diebold–Mariano test. The results demonstrated that model selection significantly influences predictive accuracy. Among the evaluated algorithms, RF achieved the highest predictive performance for AWQI (R 2 = 0.88) and C d (R 2 = 0.92), whereas ANN performed best for HPI (R 2 = 0.89), and DT yielded the most accurate predictions for MI (R 2 = 0.82). Despite the index-specific strengths of individual models, RF emerged as the most robust and generalizable approach, consistently providing superior performance across heterogeneous environmental datasets. The proposed framework advances marine water quality assessment from conventional descriptive monitoring toward a proactive, data-driven paradigm, offering a scalable and cost-effective decision support tool for environmental management, pollution mitigation, and evidence-based coastal governance in industrialized coastal regions.