Source Apportionment and Risk Assessment of Metals in the Potential Contaminated Areas

Liuyang, the primary fireworks manufacturing base in the world, is demonstrating potential metals pollution risks. In this study, 163 soil samples were collected in Liuyang City, China, for source apportionment, pollution assessment and health risk evaluation using self-organizing map, positive matrix factorization and statistical methods. Geostatistical analysis confirmed high contamination risks from Hg, Cd, Pb, and As. Samples were classified into four groups based on contamination characteristics. Pollution sources included irrigation water, fireworks enterprises, and fireworks packaging material. Cluster 1 exhibited uniformly low metals concentrations, with sampling points widely distributed across the study area. Cluster 2 samples were concentrated in the central and northern regions. The average concentration of Cr was the highest, with irrigation water contributing the most to Cr at 74%. The contribution of fireworks companies and packaging materials was 14% and 12%, respectively. Cluster 3 displayed elevated Hg and Pb levels with distinct spatial banding, where fireworks enterprises contributed 49% (Hg) and 47% (Pb), while packaging materials accounted for 37% (Hg) and 39% (Pb). Cluster 4, gathered in the southeast, showed the highest Cd and As concentrations, with fireworks companies contributing the most with 73% and 82%, respectively. Risk assessment demonstrated that children experienced greater non-carcinogenic risks from oral and dermal exposure to As, Hg, Pb, Cr, and Cd, while adults faced higher inhalation risks for Cr and Cd. Carcinogenic risks exceeded safety thresholds, with children (4.1 × 10 −9 –2.0 × 10 −4 ) more vulnerable than adults (2.9 × 10 −12 –1.4 × 10 −4 ). Asdult carcinogenic risks via ingestion dominated, whereas Cr posed greater risks for children through inhalation.