Synthesis and Characterization of Na 3 SbS 4 Solid Electrolytes via Mechanochemical and Sintered Solid-State Reactions: A Comparative Study

A sulfide-based solid electrolyte is an enticing non-organic solid-state electrolyte developed under ambient conditions. Na 3 SbS 4 , a profoundly enduring substance capable of withstanding exceedingly elevated temperatures and pressures, emerges as a focal point. Within this investigation, we employ dual distinct techniques to fabricate Na 3 SbS 4 , encompassing ball milling and the combination of ball milling with sintering procedures. A remarkable ionic conductivity of 3.1 × 10 −4 S/cm at room temperature (RT), coupled with a meager activation energy of 0.21 eV, is achieved through a bifurcated process, which is attributed to the presence of tetragonal Na 3 SbS 4 (t-NSS). Furthermore, we delve into the electrochemical performance and cyclic longevity of the Na 2/3 Fe 1/2 Mn 1/2 O 2 |t-NSS|Na system within ambient environs. It reveals 160 mAh/g initial charge and 106 mAh/g discharge capacities at 0.01 A/g current density. Furthermore, a cycle life test conducted at 0.01 A/g over 30 cycles demonstrates stable and reliable performance. The capacity retention further highlights its enduring energy storage capabilities. This study underscores the sustainable potential of Na 3 SbS 4 as a solid-state electrolyte for advanced energy storage systems.