Experimental Study on Solidification of Pb 2+ in Fly Ash-Based Geopolymers

Fly ash from the incineration of domestic waste contains heavy metals, which is harmful to the environment. To reduce and prevent their contamination, heavy metal ions need to be sequestered. In this study, the geopolymer prepared by fly ash, a kind of power plant waste, is used to cure the heavy metal Pb 2+ , and to investigate the effect of different concentrations of Pb 2+ on the compressive strength of the solidified body at different ages; the curing effect is judged by the toxic leaching concentration of heavy metals; the resistance of the solidified body to immersion is evaluated by comparing the change in strength before and after leaching; the fly ash-based geopolymer solidified body is compared with the cement solidified body in terms of curing effectiveness; the properties of the geopolymer and its mechanism of curing heavy metals are explored by microscopic tests. The results show that the fly ash-based geopolymer solidified body has good resistance to immersion; the optimum curing concentration of Pb 2+ in fly ash-based geopolymers is 2.0%; compared to pure geopolymers, the strength of the solidified body at 28 d decreases by only 13.0%, and the leaching concentration of Pb 2+ is 4.73 mg·L −1 , which meets the specification requirements; the curing effect of the fly ash-based geopolymer is better than the cement solidified body; the microscopic test results indicate that the curing of Pb 2+ by the fly ash-based geopolymer is a combination of both chemical bonding and physical fixation.