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Electrochemical Oxidation of EDTA in Nuclear Wastewater Using Platinum Supported on Activated Carbon Fibers

Author

Listed:
  • Bo Zhao

    (Key Subject Laboratory of National Defense for Radioactive Waste and Environmental Security, Southwest University of Science and Technology, Mianyang 621010, China
    School of Life Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China)

  • Wenkun Zhu

    (Key Subject Laboratory of National Defense for Radioactive Waste and Environmental Security, Southwest University of Science and Technology, Mianyang 621010, China
    Sichuan Civil-Military Integration Institute, Mianyang 621010, China)

  • Tao Mu

    (China Academy of Engineering Physics, Mianyang 621000, China)

  • Zuowen Hu

    (China Academy of Engineering Physics, Mianyang 621000, China)

  • Tao Duan

    (Key Subject Laboratory of National Defense for Radioactive Waste and Environmental Security, Southwest University of Science and Technology, Mianyang 621010, China
    Sichuan Civil-Military Integration Institute, Mianyang 621010, China)

Abstract

A novel Pt/ACF (Pt supported on activated carbon fibers) electrode was successfully prepared with impregnation and electrodeposition method. Characterization of the electrodes indicated that the Pt/ACF electrode had a larger effective area and more active sites. Electrochemical degradation of ethylenediaminetetra-acetic acid (EDTA) in aqueous solution with Pt/ACF electrodes was investigated. The results showed that the 3% Pt/ACF electrode had a better effect on EDTA removal. The operational parameters influencing the electrochemical degradation of EDTA with 3% Pt/ACF electrode were optimized and the optimal removal of EDTA and chemical oxygen demand (COD) were 94% and 60% after 100 min on condition of the electrolyte concentration, initial concentration of EDTA, current density and initial value of pH were 0.1 mol/L, 300 mg/L, 40 mA/cm 2 and 5.0, respectively. The degradation intermediates of EDTA in electrochemical oxidation with 3% Pt/ACF electrode were identified by gas chromatography-mass spectrum (GC-MS).

Suggested Citation

  • Bo Zhao & Wenkun Zhu & Tao Mu & Zuowen Hu & Tao Duan, 2017. "Electrochemical Oxidation of EDTA in Nuclear Wastewater Using Platinum Supported on Activated Carbon Fibers," IJERPH, MDPI, vol. 14(7), pages 1-11, July.
  • Handle: RePEc:gam:jijerp:v:14:y:2017:i:7:p:819-:d:105491
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