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Characterization of La/Fe/TiO 2 and Its Photocatalytic Performance in Ammonia Nitrogen Wastewater

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  • Xianping Luo

    (School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
    Western Mining Co., Ltd., Xining 81006, China
    Jiangxi Key Laboratory of Mining & Metallurgy Environmental Pollution Control, Jiangxi University of Science and Technology, Ganzhou 341000, China
    Faculty of Engineering, University of Alberta, Edmonton, AB T6G2V4, Canada)

  • Chunfei Chen

    (School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
    Jiangxi Key Laboratory of Mining & Metallurgy Environmental Pollution Control, Jiangxi University of Science and Technology, Ganzhou 341000, China)

  • Jing Yang

    (School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
    Jiangxi Key Laboratory of Mining & Metallurgy Environmental Pollution Control, Jiangxi University of Science and Technology, Ganzhou 341000, China)

  • Junyu Wang

    (School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
    Jiangxi Key Laboratory of Mining & Metallurgy Environmental Pollution Control, Jiangxi University of Science and Technology, Ganzhou 341000, China)

  • Qun Yan

    (School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
    Jiangxi Key Laboratory of Mining & Metallurgy Environmental Pollution Control, Jiangxi University of Science and Technology, Ganzhou 341000, China)

  • Huquan Shi

    (School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China)

  • Chunying Wang

    (School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
    Western Mining Co., Ltd., Xining 81006, China
    Jiangxi Key Laboratory of Mining & Metallurgy Environmental Pollution Control, Jiangxi University of Science and Technology, Ganzhou 341000, China)

Abstract

La/Fe/TiO 2 composite photocatalysts were synthesized by Sol-Gel method and well characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), nitrogen-physical adsorption, and UV-Vis diffuse reflectance spectra (UV-Vis DRS). It is interesting that the doped catalysts were in anatase phase while the pure TiO 2 was in rutile phase. In addition, the composites possessed better physical chemical properties in photocatalytic activity than pure TiO 2 : stronger visible-light-response ability, larger specific surface area, and more regular shape in morphology. The photodegradation results of ammonia nitrogen indicate that: the La/Fe/TiO 2 had higher catalytic activity to ammonia nitrogen waste water compared pure TiO 2 and the other single metal-doped TiO 2 . pH 10 and 2 mmol/L H 2 O 2 were all beneficial to the removal of ammonia nitrogen by La/Fe/TiO 2 . However, the common inorganic ions of Cl − , NO 3 − , SO 4 2− , HCO 3 − /CO 3 2 − , Na + , K + , Ca 2+ and Mg 2+ in water all inhibited the degradation of ammonia nitrogen. By balance calculation, at least 20% of ammonia nitrogen was converted to N 2 during the 64.6% removal efficiency of ammonia nitrogen.

Suggested Citation

  • Xianping Luo & Chunfei Chen & Jing Yang & Junyu Wang & Qun Yan & Huquan Shi & Chunying Wang, 2015. "Characterization of La/Fe/TiO 2 and Its Photocatalytic Performance in Ammonia Nitrogen Wastewater," IJERPH, MDPI, vol. 12(11), pages 1-14, November.
  • Handle: RePEc:gam:jijerp:v:12:y:2015:i:11:p:14626-14639:d:58952
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    References listed on IDEAS

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    1. Samuel S. R. Dasary & Julia Saloni & Amanda Fletcher & Yerramilli Anjaneyulu & Hongtao Yu, 2010. "Photodegradation of Selected PCBs in the Presence of Nano-TiO 2 as Catalyst and H 2 O 2 as an Oxidant," IJERPH, MDPI, vol. 7(11), pages 1-15, November.
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