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Glucose-Treated Manganese Hexacyanoferrate for Sodium-Ion Secondary Battery

Author

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  • Yutaka Moritomo

    (Graduate School of Pure and Applied Science, University of Tsukuba, Tsukuba 305-8577, Japan
    Faculty of Pure and Applied Science, University of Tsukuba, Tsukuba 305-8577, Japan
    Center for Integrated Research in Fundamental Science and Engineering (CiRfSE), University of Tsukuba, Tsukuba 305-8577, Japan)

  • Kensuke Goto

    (Graduate School of Pure and Applied Science, University of Tsukuba, Tsukuba 305-8577, Japan
    These authors contributed equally to this work.)

  • Takayuki Shibata

    (Graduate School of Pure and Applied Science, University of Tsukuba, Tsukuba 305-8577, Japan
    Faculty of Pure and Applied Science, University of Tsukuba, Tsukuba 305-8577, Japan
    These authors contributed equally to this work.)

Abstract

Manganese hexacyanoferrate (Mn-PBA) is a promising cathode material forsodium-ion secondary battery (SIB) with high average voltage (=3.4 V) against Na. Here,we find that the thermal decomposition of glucose modifies the surface state of Mn-PBA,without affecting the bulk crystal structure. The glucose treatment significantly improves therate properties of Mn-PBA in SIB. The critical discharge rate increases from 1 C (as-grown)to 15 C (glucose-treated). Our observation suggests that thermal treatment is quite effectivefor insulating coordination polymers.

Suggested Citation

  • Yutaka Moritomo & Kensuke Goto & Takayuki Shibata, 2015. "Glucose-Treated Manganese Hexacyanoferrate for Sodium-Ion Secondary Battery," Energies, MDPI, vol. 8(9), pages 1-9, September.
  • Handle: RePEc:gam:jeners:v:8:y:2015:i:9:p:9486-9494:d:55115
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