IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v18y2025i13p3302-d1686155.html
   My bibliography  Save this article

Fuel Features of Straw Biomass Valorized with Aluminosilicates

Author

Listed:
  • Joanna Wnorowska

    (Department of Power Engineering and Turbomachinery, Faculty of Energy and Environmental Engineering, Silesian University of Technology, Konarskiego 18, 44-100 Gliwice, Poland)

  • Mateusz Tymoszuk

    (Department of Power Engineering and Turbomachinery, Faculty of Energy and Environmental Engineering, Silesian University of Technology, Konarskiego 18, 44-100 Gliwice, Poland)

  • Sylwester Kalisz

    (Department of Power Engineering and Turbomachinery, Faculty of Energy and Environmental Engineering, Silesian University of Technology, Konarskiego 18, 44-100 Gliwice, Poland)

Abstract

Straw biomass is a renewable but problematic fuel due to its high alkali and chlorine content, which can cause slagging and corrosion during combustion. To mitigate these issues, this study investigates the influence of aluminosilicate additives on the thermal behavior and combustion characteristics of straw biomass. Laboratory-scale testing is carried out using thermogravimetric analysis under atmospheric air, showing the TG, DTG, and DSC profiles of samples (kaolinite, halloysite, straw biomass, and straw biomass with 4 wt.% of halloysite). Additionally, the main combustion parameters, like the ignition temperature, the maximum peak temperature, the burnout temperature, and some combustion indexes, are presented. The results show the effect of a heating rate in the range of 5–20 °C/min. Moreover, in this study, two non-isothermal model methods (Kissinger and Ozawa) are used to estimate energy activation. While halloysite slightly affects the combustion indexes and marginally reduces energy activation, its overall influence does not significantly alter combustion efficiency. These findings support the potential and safe use of halloysite for the biomass combustion process.

Suggested Citation

  • Joanna Wnorowska & Mateusz Tymoszuk & Sylwester Kalisz, 2025. "Fuel Features of Straw Biomass Valorized with Aluminosilicates," Energies, MDPI, vol. 18(13), pages 1-13, June.
    • Handle: RePEc:gam:jeners:v:18:y:2025:i:13:p:3302-:d:1686155
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/18/13/3302/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/18/13/3302/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Míguez, José Luis & Porteiro, Jacobo & Behrendt, Frank & Blanco, Diana & Patiño, David & Dieguez-Alonso, Alba, 2021. "Review of the use of additives to mitigate operational problems associated with the combustion of biomass with high content in ash-forming species," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    2. Gollmer, Christian & Höfer, Isabel & Kaltschmitt, Martin, 2021. "Laboratory-scale additive content assessment for aluminum-silicate-based wood chip additivation," Renewable Energy, Elsevier, vol. 164(C), pages 1471-1484.
    3. Joanna Wnorowska & Szymon Ciukaj & Sylwester Kalisz, 2021. "Thermogravimetric Analysis of Solid Biofuels with Additive under Air Atmosphere," Energies, MDPI, vol. 14(8), pages 1-19, April.
    4. Paniagua Bermejo, Sergio & Prado-Guerra, Alba & García Pérez, Ana Isabel & Calvo Prieto, Luis Fernando, 2020. "Study of quinoa plant residues as a way to produce energy through thermogravimetric analysis and indexes estimation," Renewable Energy, Elsevier, vol. 146(C), pages 2224-2233.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Garikai T. Marangwanda & Daniel M. Madyira & Patrick G. Ndungu & Chido H. Chihobo, 2021. "Combustion Characterisation of Bituminous Coal and Pinus Sawdust Blends by Use of Thermo-Gravimetric Analysis," Energies, MDPI, vol. 14(22), pages 1-19, November.
    2. Christian Gollmer & Vanessa Weigel & Martin Kaltschmitt, 2023. "Emission Mitigation by Aluminum-Silicate-Based Fuel Additivation of Wood Chips with Kaolin and Kaolinite," Energies, MDPI, vol. 16(7), pages 1-17, March.
    3. Nataša Dragutinović & Isabel Höfer & Martin Kaltschmitt, 2021. "Fuel Improvement Measures for Particulate Matter Emission Reduction during Corn Cob Combustion," Energies, MDPI, vol. 14(15), pages 1-23, July.
    4. Prayoga, Moch Zulfikar Eka & Putra, Hanafi Prida & Wargadalam, Verina Januati & Surachman, Hadi & Luktyansyah, Insyiah Meida & Saudah, Siti & Darmawan, Arif & Aziz, Muhammad & Prabowo, Prabowo & Wang,, 2025. "Thermal characteristics and slagging-fouling analysis in co-combustion of coal and oil palm waste mixtures," Energy, Elsevier, vol. 319(C).
    5. Espinoza-Monje, J. Flavio & Garcés, Hugo O. & Díaz, Juan & Adam, Roman & Lazo, Jorge & Muñoz, Robinson & Coronado, Matías & Saiz, Gustavo & Azócar, Laura, 2024. "Investigating the properties of shrub biomass pellets through additive and sawdust admixing," Renewable Energy, Elsevier, vol. 229(C).
    6. Joanna Wnorowska & Szymon Ciukaj & Sylwester Kalisz, 2021. "Thermogravimetric Analysis of Solid Biofuels with Additive under Air Atmosphere," Energies, MDPI, vol. 14(8), pages 1-19, April.
    7. Zoran Čepić & Višnja Mihajlović & Slavko Đurić & Milan Milotić & Milena Stošić & Borivoj Stepanov & Milana Ilić Mićunović, 2021. "Experimental Analysis of Temperature Influence on Waste Tire Pyrolysis," Energies, MDPI, vol. 14(17), pages 1-11, August.
    8. Hariana, & Ghazidin, Hafizh & Putra, Hanafi Prida & Darmawan, Arif & Prabowo, & Hilmawan, Edi & Aziz, Muhammad, 2023. "The effects of additives on deposit formation during co-firing of high-sodium coal with high-potassium and -chlorine biomass," Energy, Elsevier, vol. 271(C).
    9. Ghazidin, Hafizh & Suyatno, Suyatno & Prismantoko, Adi & Ruhiyat, Ade Sana & Prabowo, & Darmawan, Arif & Soleh, Mochamad & Aziz, Amiral & Asmanto, Puji & Vuthaluru, Hari & Wang, Yibin & Yurismono, Har, 2025. "Control of slagging and fouling during co-firing of solid recovered fuel and high-sodium coal using aluminum and magnesium-based additives," Energy, Elsevier, vol. 318(C).
    10. Yuan, Mengran & Guo, Jing & He, Chong & Ilyushechkin, Alexander & Li, Xiaoming & Lu, Hao & Fan, Feifei & Wang, Zhigang & Qin, Yuhong & Wei, Yuexing & Bai, Jin & Li, Wen, 2025. "Structure-governed potassium retention mechanism in the slagging and non-slagging gasification condition of corn straw," Renewable Energy, Elsevier, vol. 239(C).
    11. Shiqiao Yang & Ming Lei & Min Li & Chao Liu & Beichen Xue & Rui Xiao, 2022. "Comprehensive Estimation of Combustion Behavior and Thermochemical Structure Evolution of Four Typical Industrial Polymeric Wastes," Energies, MDPI, vol. 15(7), pages 1-22, March.
    12. Ghazidin, Hafizh & Suyatno, Suyatno & Prismantoko, Adi & Karuana, Feri & Sarjono, & Prabowo, & Setiyawan, Atok & Darmawan, Arif & Aziz, Muhammad & Vuthaluru, Hari & Hariana, Hariana, 2024. "Impact of additives in mitigating ash-related problems during co-combustion of solid recovered fuel and high-sulfur coal," Energy, Elsevier, vol. 292(C).
    13. Natalia Cid & Juan Jesús Rico & Raquel Pérez-Orozco & Ana Larrañaga, 2021. "Experimental Study of the Performance of a Laboratory-Scale ESP with Biomass Combustion: Discharge Electrode Disposition, Dynamic Control Unit and Aging Effect," Sustainability, MDPI, vol. 13(18), pages 1-12, September.
    14. Krzysztof M. Czajka, 2025. "Evaluation of the Reliability of Thermogravimetric Indices for Predicting Coal Performance in Utility Systems," Energies, MDPI, vol. 18(13), pages 1-36, July.
    15. Vinay Atgur & G. Manavendra & Nagaraj R. Banapurmath & Boggarapu Nageswar Rao & Ali A. Rajhi & T. M. Yunus Khan & Chandramouli Vadlamudi & Sanjay Krishnappa & Ashok M. Sajjan & R. Venkatesh, 2022. "Essence of Thermal Analysis to Assess Biodiesel Combustion Performance," Energies, MDPI, vol. 15(18), pages 1-23, September.
    16. Mohammed, Habu Iyodo & Garba, Kabir & Ahmed, Saeed I. & Abubakar, Lawan G., 2022. "Thermodynamics and kinetics of Doum (Hyphaene thebaica) shell using thermogravimetric analysis: A study on pyrolysis pathway to produce bioenergy," Renewable Energy, Elsevier, vol. 200(C), pages 1275-1285.
    17. Zhang, Jianan & Wang, Yuesen & Muldoon, Valerie L. & Deng, Sili, 2022. "Crude glycerol and glycerol as fuels and fuel additives in combustion applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    18. Ma, Changhao & Tian, Haoyu & Ma, Yuchen & Du, Bingjun & Zhang, Yang & Lyu, Junfu & Ke, Xiwei, 2025. "Experimental investigation on the effect of iron-rich coal ash on biomass-volatile combustion characteristics in the fluidized bed," Energy, Elsevier, vol. 321(C).
    19. Li, Yu & Tan, Zhiwu & Zhu, Youjian & Zhang, Wennan & Du, Zhenyi & Shao, Jingai & Jiang, Long & Yang, Haiping & Chen, Hanping, 2022. "Effects of P-based additives on agricultural biomass torrefaction and particulate matter emissions from fuel combustion," Renewable Energy, Elsevier, vol. 190(C), pages 66-77.
    20. González-Arias, J. & Gómez, X. & González-Castaño, M. & Sánchez, M.E. & Rosas, J.G. & Cara-Jiménez, J., 2022. "Insights into the product quality and energy requirements for solid biofuel production: A comparison of hydrothermal carbonization, pyrolysis and torrefaction of olive tree pruning," Energy, Elsevier, vol. 238(PC).

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:18:y:2025:i:13:p:3302-:d:1686155. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.