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Methane Hydrate Behavior for Water–Oil Systems Containing CTAB and Synperonic PE/F127 Surfactants

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  • Antonio Pavón-García

    (Departamento de Ingeniería Química Petrolera and Sección de Estudios de Posgrado e Investigación, Escuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, UPALM, Ed. 8, Lindavista, Ciudad de México 07738, Mexico)

  • Abel Zúñiga-Moreno

    (Laboratorio de Investigación en Fisicoquímica y Materiales, Departamento de Ingeniería Química Industrial, Escuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, Edif. Z-5, 2° piso, UPALM, Lindavista, Ciudad de México 07738, Mexico)

  • Ricardo García-Morales

    (Departamento de Ingeniería Química Petrolera and Sección de Estudios de Posgrado e Investigación, Escuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, UPALM, Ed. 8, Lindavista, Ciudad de México 07738, Mexico)

  • Hugo I. Pérez-López

    (Departamento de Ingeniería Química Petrolera and Sección de Estudios de Posgrado e Investigación, Escuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, UPALM, Ed. 8, Lindavista, Ciudad de México 07738, Mexico)

  • Octavio Elizalde-Solis

    (Departamento de Ingeniería Química Petrolera and Sección de Estudios de Posgrado e Investigación, Escuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, UPALM, Ed. 8, Lindavista, Ciudad de México 07738, Mexico)

Abstract

Methane hydrates were studied in systems containing aqueous dissolved surfactants in oil emulsions with a volume ratio of 40/60. Two commercial surfactants, named synperonic PE/F127 and cetyltrimethylammonium bromide, were evaluated at 0, 350, 700 and 1500 ppm. Experiments were made by applying the cooling–heating path in an isochoric high-pressure cell at different initial pressures of 5.5, 8.0, 10.0 and 12.0 MPa. The obtained parameters were induction time, temperature onset, pressure drop, and dissociation conditions. The results revealed that the dissociation curve for methane in water-in-oil emulsions was not modified by the surfactants. The crystallization (onset) temperature was higher using synperonic PE/F127 in comparison with zero composition, while the opposite occurred with cetyltrimethylammonium bromide. Both surfactants induced a delaying effect on the induction time and a lesser pressure drop.

Suggested Citation

  • Antonio Pavón-García & Abel Zúñiga-Moreno & Ricardo García-Morales & Hugo I. Pérez-López & Octavio Elizalde-Solis, 2022. "Methane Hydrate Behavior for Water–Oil Systems Containing CTAB and Synperonic PE/F127 Surfactants," Energies, MDPI, vol. 15(14), pages 1-13, July.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:14:p:5213-:d:865759
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    Cited by:

    1. Alexey Dengaev & Vladimir Verbitsky & Olga Eremenko & Anna Novikova & Andrey Getalov & Boris Sargin, 2022. "Water-in-Oil Emulsions Separation Using a Controlled Multi-Frequency Acoustic Field at an Operating Facility," Energies, MDPI, vol. 15(17), pages 1-16, August.

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