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Influence of Oxygen Ion Migration from Substrates on Photochemical Degradation of CH 3 NH 3 PbI 3 Hybrid Perovskite

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  • Ivan S. Zhidkov

    (Institute of Physics and Technology, Ural Federal University, Mira St. 19, 620002 Yekaterinburg, Russia
    M. N. Mikheev Institute of Metal Physics of Ural Branch of Russian Academy of Sciences, S. Kovalevskoi St. 18, 620108 Yekaterinburg, Russia)

  • Azat F. Akbulatov

    (Institute for Problems of Chemical Physics, The Russian Academy of Sciences (IPCP RAS), Semenov Prospect 1, 141432 Chernogolovka, Russia)

  • Liana N. Inasaridze

    (Institute for Problems of Chemical Physics, The Russian Academy of Sciences (IPCP RAS), Semenov Prospect 1, 141432 Chernogolovka, Russia)

  • Andrey I. Kukharenko

    (Institute of Physics and Technology, Ural Federal University, Mira St. 19, 620002 Yekaterinburg, Russia)

  • Lyubov A. Frolova

    (Institute for Problems of Chemical Physics, The Russian Academy of Sciences (IPCP RAS), Semenov Prospect 1, 141432 Chernogolovka, Russia)

  • Seif O. Cholakh

    (Institute of Physics and Technology, Ural Federal University, Mira St. 19, 620002 Yekaterinburg, Russia)

  • Chu-Chen Chueh

    (Advanced Research Center for Green Materials Science and Technology, Department of Chemical Engineering, National Taiwan University, Taipei 10617, Taiwan)

  • Pavel A. Troshin

    (Institute for Problems of Chemical Physics, The Russian Academy of Sciences (IPCP RAS), Semenov Prospect 1, 141432 Chernogolovka, Russia)

  • Ernst Z. Kurmaev

    (Institute of Physics and Technology, Ural Federal University, Mira St. 19, 620002 Yekaterinburg, Russia
    M. N. Mikheev Institute of Metal Physics of Ural Branch of Russian Academy of Sciences, S. Kovalevskoi St. 18, 620108 Yekaterinburg, Russia)

Abstract

Measurements of XPS survey, core levels (N 1s, O 1s, Pb 4f, I 3d), and valence band (VB) spectra of CH 3 NH 3 PbI 3 (MAPbI 3 ) hybrid perovskite prepared on different substrates (glass, indium tin oxide (ITO), and TiO 2 ) aged under different light-soaking conditions at room temperature are presented. The results reveal that the photochemical stability of MAPbI 3 depends on the type of substrate and gradually decreases when glass is replaced by ITO and TiO 2 . Also, the degradation upon exposure to visible light is accompanied by the formation of MAI, PbI 2 , and Pb 0 products as shown by XPS core levels spectra. According to XPS O 1s and VB spectra measurements, this degradation process is superimposed on the partial oxidation of lead atoms in ITO/MAPbI 3 and TiO 2 /MAPbI 3 , for which Pb–O bonds are formed due to the diffusion of the oxygen ions from the substrates. This unexpected interaction leads to additional photochemical degradation.

Suggested Citation

  • Ivan S. Zhidkov & Azat F. Akbulatov & Liana N. Inasaridze & Andrey I. Kukharenko & Lyubov A. Frolova & Seif O. Cholakh & Chu-Chen Chueh & Pavel A. Troshin & Ernst Z. Kurmaev, 2021. "Influence of Oxygen Ion Migration from Substrates on Photochemical Degradation of CH 3 NH 3 PbI 3 Hybrid Perovskite," Energies, MDPI, vol. 14(16), pages 1-9, August.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:16:p:5062-:d:616324
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    References listed on IDEAS

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    1. Hernan Sanchez Casalongue & Sarp Kaya & Venkatasubramanian Viswanathan & Daniel J. Miller & Daniel Friebel & Heine A. Hansen & Jens K. Nørskov & Anders Nilsson & Hirohito Ogasawara, 2013. "Direct observation of the oxygenated species during oxygen reduction on a platinum fuel cell cathode," Nature Communications, Nature, vol. 4(1), pages 1-6, December.
    2. Alessandra Alberti & Corrado Bongiorno & Emanuele Smecca & Ioannis Deretzis & Antonino La Magna & Corrado Spinella, 2019. "Pb clustering and PbI2 nanofragmentation during methylammonium lead iodide perovskite degradation," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
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