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A Surfactant for Enhanced Heavy Oil Recovery in Carbonate Reservoirs in High-Salinity and High-Temperature Conditions

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  • Yu-Qi Yang

    (Unconventional Oil and Gas Science and Technology Institute, China University of Petroleum, Beijing 102249, China
    State Key Laboratory of Heavy Oil Processing at Karamay, China University of Petroleum-Beijing at Karamay, Karamay 834000, China)

  • Liang Li

    (Unconventional Oil and Gas Science and Technology Institute, China University of Petroleum, Beijing 102249, China
    SINOPEC Northwest Oil Field Company, Urumchi 830011, China)

  • Xiang Wang

    (Unconventional Oil and Gas Science and Technology Institute, China University of Petroleum, Beijing 102249, China)

  • Yue-Qun Fu

    (NTNU Nanomechanical Lab, Norwegian University of Science and Technology (NTNU), 7491 Trondheim, Norway)

  • Xiao-Qing He

    (SINOPEC Northwest Oil Field Company, Urumchi 830011, China)

  • Shi-Ling Zhang

    (Unconventional Oil and Gas Science and Technology Institute, China University of Petroleum, Beijing 102249, China)

  • Ji-Xiang Guo

    (Unconventional Oil and Gas Science and Technology Institute, China University of Petroleum, Beijing 102249, China)

Abstract

In view of the difficulty of producing heavy oil from carbonate reservoirs, the surfactant SDY-1 was synthesized by homogeneous solution polymerization with a homogeneous solution polymerization technique using aliphatic amine polyoxyethylene ether (PAE n ) H(OCH 2 CH 2 ) n NR(CH 2 CH 2 O) n H as the raw material, epichlorohydrin as the reaction intermediate, tetrabutylammonium bromide and pentamethyldivinyltriamine as the promoters, and alkylphenol as the catalyst. Based on the analysis of reservoir fluid and rock properties, the performance of the surfactant SDY-1 was evaluated in terms of its heat resistance, its salinity tolerance, its ability to change the heavy oil–water interfacial tension and rock wettability and its oil washing efficiency. The results show that when the salinity of the formation water is 2.23 × 10 5 mg/L, the addition of surfactant SDY-1 can lower the super-heavy oil–water interfacial tension with an asphaltene concentration of 30.19 wt.%, which is aged at a temperature of 140 °C for 3 days, from 22.41 to 0.366 mN/m. In addition, the surfactant SDY-1 can change the contact angle of super-heavy oil–water–rock from 129.7 to 67.4° and reduce the adhesion of crude oil to the rock surface by 99.26%. The oil displacement experiment indicates that the oil washing efficiency of the surfactant SDY-1 can reach 78.7% after ageing at a temperature of 140 °C for 3 days. Compared with petroleum sulfonate flooding, the addition of SDY-1 can improve the displacement efficiency by 33.6%, and the adsorption loss is only 0.651 mg/g oil sand. It has broad application prospects for heavy oil reservoirs with high temperatures, high pressures and high asphaltene contents.

Suggested Citation

  • Yu-Qi Yang & Liang Li & Xiang Wang & Yue-Qun Fu & Xiao-Qing He & Shi-Ling Zhang & Ji-Xiang Guo, 2020. "A Surfactant for Enhanced Heavy Oil Recovery in Carbonate Reservoirs in High-Salinity and High-Temperature Conditions," Energies, MDPI, vol. 13(17), pages 1-15, September.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:17:p:4525-:d:407172
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    References listed on IDEAS

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    1. S. M. Shakil Hussain & Muhammad Shahzad Kamal & Mobeen Murtaza, 2019. "Synthesis of Novel Ethoxylated Quaternary Ammonium Gemini Surfactants for Enhanced Oil Recovery Application," Energies, MDPI, vol. 12(9), pages 1-16, May.
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    Cited by:

    1. Pål Østebø Andersen & Ketil Djurhuus & Reza Askarinezhad & Jonas S. Solbakken, 2022. "Management of High-Water-Cut and Mature Petroleum Reservoirs," Energies, MDPI, vol. 15(22), pages 1-4, November.

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