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Photoluminescent Enhancement by Effect of Incorporation Nickel in ZnO Films Grown

Author

Listed:
  • Delfino R. Gutiérrez

    (Universidad Autónoma de Puebla, México)

  • Tomás Díaz-Becerril

    (Universidad Autónoma de Puebla, México)

  • Godofredo García-Salgado

    (Universidad Autónoma de Puebla, México)

  • Antonio Coyopol-Solís

    (Universidad Autónoma de Puebla, México)

  • Enrique Rosendo-Andrés

    (Universidad Autónoma de Puebla, México)

  • Reina Galeazzi-Isasmendi

    (Universidad Autónoma de Puebla, México)

  • Ramón Peña-Sierra

    (Universidad Autónoma de Puebla, México)

  • Crisóforo Morales-Ruiz

    (Universidad Autónoma de Puebla, México)

  • Roman Romano-Trujillo

    (Universidad Autónoma de Puebla, México)

  • Fabiola G. Nieto-Caballero

    (Universidad Autónoma de Puebla, México)

Abstract

Microstructured films of undoped zinc oxide (ZnO) and ZnO doped with nickel (ZnO:Ni) were grown by hot filament chemical vapor deposition (HFCVD) technique on Si (100) substrates at 500 °C. Pellets of ZnO and ZnO:NiO as oxidant agenst were used. A shift to the right around 0.17 degree of the X-Ray Diffraction pattern of the ZnO:Ni film was observed with respect to undoped ZnO films. Morphologically by Scanning Electron Microscopy was noticed a Core-Shell type growth in ZnO undoped and a nanostructured type (Nano-wire) in ZnO doped with Ni. Photoluminescence measurements showed an increase in the intensity of the green emission band of ZnO:Ni. It was attributed to defects of oxygen vacancies (VO), zinc vacancies (VZn), zinc interstitials (Zni), oxygen interstitials (Oi), and oxygen vacancies complex (VO complex) in the structure of the film. The incorporation of Ni atoms in the ZnO structure stresses the crystal lattice, leaving behind a large number of surface defects that increase the emission of PL.

Suggested Citation

  • Delfino R. Gutiérrez & Tomás Díaz-Becerril & Godofredo García-Salgado & Antonio Coyopol-Solís & Enrique Rosendo-Andrés & Reina Galeazzi-Isasmendi & Ramón Peña-Sierra & Crisóforo Morales-Ruiz & Roman R, 2021. "Photoluminescent Enhancement by Effect of Incorporation Nickel in ZnO Films Grown," European Journal of Engineering and Technology Research, European Open Science, vol. 6(5), pages 177-180, July.
  • Handle: RePEc:epw:ejeng0:v:6:y:2021:i:5:id:62550
    DOI: 10.24018/ejeng.2021.6.5.2550
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