IDEAS home Printed from https://ideas.repec.org/a/epw/ejeng0/v4y2019i7id61382.html

Effect of Dielectric Constant of Medium on Conductance for Trimethylsulfonium Halides in Normal and Branched Alcohols

Author

Listed:
  • Nasr H. El-Hammamy

    (Department of Chemistry, Faculty of Science, Alexandria University, Alexandria, Egypt)

  • Marwa A. Daghash

    (Department of Chemistry, Faculty of Science, Alexandria University, Alexandria, Egypt)

  • Aida I. Kawana

    (Department of Chemistry, Faculty of Education, Alexandria University, Alexandria, Egypt)

Abstract

The conductance parameters, ?o (equivalent conductance at infinite dilution) and KA (association constant) for trimethylsulfonium halides (Bromide and Iodide) in methanol, ethanol, n-propanol, 2-propanol and n-butanol have been evaluated at 25°C from the conductance measurements. The values of ?o for different salts decrease with decreasing dielectric constant of medium (D) with some variations and are in the order of MeOH > EtOH > n-PrOH > 2-PrOH > n-BuOH. The association constants of the same salts in different alcohols increase with decreasing dielectric constant of medium and are in the order of n-BuOH > 2-PrOH > n-PrOH > EtOH > MeOH.

Suggested Citation

  • Nasr H. El-Hammamy & Marwa A. Daghash & Aida I. Kawana, 2019. "Effect of Dielectric Constant of Medium on Conductance for Trimethylsulfonium Halides in Normal and Branched Alcohols," European Journal of Engineering and Technology Research, European Open Science, vol. 4(7), pages 18-20, July.
    • Handle: RePEc:epw:ejeng0:v:4:y:2019:i:7:id:61382
    DOI: 10.24018/ejeng.2019.4.7.1382
    as

    Download full text from publisher

    File URL: https://eu-opensci.org/index.php/ejeng/article/view/61382
    File Function: Abstract page
    Download Restriction: no
    File URL: https://eu-opensci.org/index.php/ejeng/article/download/61382/12169
    File Function: Full text
    Download Restriction: no
    File URL: https://libkey.io/10.24018/ejeng.2019.4.7.1382?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    More about this item

    Keywords

    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:epw:ejeng0:v:4:y:2019:i:7:id:61382. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Support (email available below). General contact details of provider: https://eu-opensci.org/index.php/ejeng .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.