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Corrosion Inhibition and Sustainable Waste Management: Evaluating the Potential of Expired Lopinavir-Ritonavir in Steel Protection

Author

Listed:
  • Suleiman Bulama

    (Department of Chemistry Abubakar Tafawa Balewa University Bauchi P.M.B 0248 Bauchi State)

  • Alhaji M. Kolo

    (Department of Chemistry Abubakar Tafawa Balewa University Bauchi P.M.B 0248 Bauchi State)

  • Istafinus. Y. Chindo

    (Department of Chemistry Abubakar Tafawa Balewa University Bauchi P.M.B 0248 Bauchi State)

  • Auwal. A. Mahmoud

    (Department of Chemistry Abubakar Tafawa Balewa University Bauchi P.M.B 0248 Bauchi State)

  • Dahiru Ibrahim

    (Nigerian Army University Biu No. 1 Gombe Road, P.M.B 1500 Biu, Borno State)

Abstract

This study investigated the potential of expired Lopinavir-Ritonavir (LPV-RTV) co-formulated antiretroviral drug, a pharmaceutical waste product, as a corrosion inhibitor for mild steel. The corrosion inhibition efficiency of expired LPV-RTV was evaluated through three complementary methods: weight loss, potentiodynamic polarization (PDP), and Scanning Electron Microscopy with Energy Dispersive X-ray Spectroscopy (SEM-EDX). The results demonstrated that expired LPV-RTV significantly enhanced the corrosion resistance of mild steel, achieving maximum inhibition efficiencies of 95.7% by weight loss and 93.0% by PDP. SEM-EDX analysis of the steel surfaces revealed the formation of a protective layer, further supporting the corrosion inhibition mechanism. These findings highlight the effectiveness of expired LPV-RTV as an efficient, eco-friendly corrosion inhibitor. The study also emphasizes the potential of utilizing expired pharmaceuticals for sustainable resource recovery, offering a viable solution for both pharmaceutical waste reduction and industrial corrosion control.

Suggested Citation

  • Suleiman Bulama & Alhaji M. Kolo & Istafinus. Y. Chindo & Auwal. A. Mahmoud & Dahiru Ibrahim, 2026. "Corrosion Inhibition and Sustainable Waste Management: Evaluating the Potential of Expired Lopinavir-Ritonavir in Steel Protection," International Journal of Research and Innovation in Applied Science, International Journal of Research and Innovation in Applied Science (IJRIAS), vol. 11(3), pages 468-482, March.
  • Handle: RePEc:bjf:journl:v:11:y:2026:i:3:p:468-482
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