IDEAS home Printed from https://ideas.repec.org/a/asi/joasrj/v5y2015i9p473-481id3746.html
   My bibliography  Save this article

Synthesis and Structural Investigations of Layered Perovskite System: [NH3-(CH2)3-COOH]2MCL4 ( M= Cd, Hg)

Author

Listed:
  • Mahmoud Ettakni
  • Abdellah Kaiba
  • Jawad Aazza
  • F Haiki
  • Mostafa Khechoubi

Abstract

A new organic-inorganic hybrids [NH3-(CH2)3-COOH]2 MCl4( M= Hg, Cd) were synthesized; the single crystals were obtained by diffusion voice at room temperature. The structures were solved from single-crystal X-ray diffraction at room temperature. The first compound [NH3-(CH2)3-COOH]2HgCl4 (1) crystallizes in the monoclinic system with C2/c space group, a=29.2762(2) Å, b=11.0408(1) Å, c=11.3944(1) Å, β=112.532(2)˚ and Z=8. The second compound [NH3-(CH2)3-COOH]2CdCl4 (2) crystallizes in the monoclinic system with P21 space group, a= 7.409(1) Å, b= 7.490(1) Å, c= 15.298(2) Å, β = 100.084(2)˚ and Z=2. The both structures might be described two dimensional layered systems with two parallel anionic and cationic layers. Three dimensional network of hydrogen – bonding assures the cohesion between these layers and stabilizes the crystal. In this work we present the comparison of both structures and we show the influence of the metal nature in the crystalline structure.

Suggested Citation

  • Mahmoud Ettakni & Abdellah Kaiba & Jawad Aazza & F Haiki & Mostafa Khechoubi, 2015. "Synthesis and Structural Investigations of Layered Perovskite System: [NH3-(CH2)3-COOH]2MCL4 ( M= Cd, Hg)," Journal of Asian Scientific Research, Asian Economic and Social Society, vol. 5(9), pages 473-481.
    • Handle: RePEc:asi:joasrj:v:5:y:2015:i:9:p:473-481:id:3746
    as

    Download full text from publisher

    File URL: https://archive.aessweb.com/index.php/5003/article/view/3746/5921
    Download Restriction: no
    ---><---

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:asi:joasrj:v:5:y:2015:i:9:p:473-481:id:3746. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Robert Allen (email available below). General contact details of provider: https://archive.aessweb.com/index.php/5003/ .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.