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Sustainable coffee†based CO2 adsorbents: toward a greener production via hydrothermal carbonization

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  • Nausika Querejeta
  • M. Victoria Gil
  • Fernando Rubiera
  • Covadonga Pevida

Abstract

Activated carbons for adsorption of CO2 under flue gas conditions were prepared by means of hydrothermal carbonization (HTC) and subsequent CO2 activation of spent coffee grounds. The HTC of the samples consisted of their heating at moderate temperature with a high water content in autoclave. A preliminary screening concluded that 1:2 biomass/water ratio (spent coffee grounds as received) and no chemicals added during HTC with further activation in CO2 at 800°C for 1 h are suitable conditions to produce the CO2 adsorbents. In addition, the response surface methodology (RSM) successfully evaluated the combined effect of HTC temperature and dwell time, to maximize the CO2 capture capacity within the experimental region. Both the lowest temperature and dwell time (120°C, 3 h) resulted in the maximum CO2 capture capacity (2.95 wt.%). Two activated carbons (ACs) were then produced: one via hydrothermal carbonization optimized by means of response surface methodology (RSM) followed by CO2 activation (HC†Co) and the other one by single†step CO2 activation as described in the Group's patent ES2526259 (AC†Co). Analysis of the features and performances of the two ACs revealed superior chemical and textural characteristics on HC†Co for CO2 adsorption under post†combustion capture conditions; HTC process is the sole responsible of this enhancement. Moreover, the proposed methodology to produce CO2 adsorbents from spent coffee grounds represents a more energy†efficient approach. © 2017 Society of Chemical Industry and John Wiley & Sons, Ltd.

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  • Nausika Querejeta & M. Victoria Gil & Fernando Rubiera & Covadonga Pevida, 2018. "Sustainable coffee†based CO2 adsorbents: toward a greener production via hydrothermal carbonization," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 8(2), pages 309-323, April.
    • Handle: RePEc:wly:greenh:v:8:y:2018:i:2:p:309-323
    DOI: 10.1002/ghg.1740
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    References listed on IDEAS

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    1. Plaza, M.G. & González, A.S. & Pevida, C. & Pis, J.J. & Rubiera, F., 2012. "Valorisation of spent coffee grounds as CO2 adsorbents for postcombustion capture applications," Applied Energy, Elsevier, vol. 99(C), pages 272-279.
    2. Zhao, Peitao & Shen, Yafei & Ge, Shifu & Chen, Zhenqian & Yoshikawa, Kunio, 2014. "Clean solid biofuel production from high moisture content waste biomass employing hydrothermal treatment," Applied Energy, Elsevier, vol. 131(C), pages 345-367.
    3. Plaza, M.G. & Durán, I. & Rubiera, F. & Pevida, C., 2015. "CO2 adsorbent pellets produced from pine sawdust: Effect of coal tar pitch addition," Applied Energy, Elsevier, vol. 144(C), pages 182-192.
    4. Hao, Wenming & Björkman, Eva & Lilliestråle, Malte & Hedin, Niklas, 2013. "Activated carbons prepared from hydrothermally carbonized waste biomass used as adsorbents for CO2," Applied Energy, Elsevier, vol. 112(C), pages 526-532.
    5. Kambo, Harpreet Singh & Dutta, Animesh, 2015. "A comparative review of biochar and hydrochar in terms of production, physico-chemical properties and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 45(C), pages 359-378.
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    1. García, R. & Gil, M.V. & Fanjul, A. & González, A. & Majada, J. & Rubiera, F. & Pevida, C., 2021. "Residual pyrolysis biochar as additive to enhance wood pellets quality," Renewable Energy, Elsevier, vol. 180(C), pages 850-859.
    2. René A. Garrido & Camila Lagos & Carolina Luna & Jaime Sánchez & Georgina Díaz, 2021. "Study of the Potential Uses of Hydrochar from Grape Pomace and Walnut Shells Generated from Hydrothermal Carbonization as an Alternative for the Revalorization of Agri-Waste in Chile," Sustainability, MDPI, vol. 13(22), pages 1-10, November.
    3. Marcelina Sołtysik & Izabela Majchrzak-Kucęba & Dariusz Wawrzyńczak, 2022. "Bio-Waste as a Substitute for the Production of Carbon Dioxide Adsorbents: A Review," Energies, MDPI, vol. 15(19), pages 1-23, September.

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