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Tensile straining of iridium sites in manganese oxides for proton-exchange membrane water electrolysers

Author

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  • Hui Su

    (College of Chemistry and Chemical Engineering, Hunan Normal University)

  • Chenyu Yang

    (University of Science and Technology of China)

  • Meihuan Liu

    (Central South University)

  • Xu Zhang

    (Faculty of Materials and Manufacturing, Beijing University of Technology)

  • Wanlin Zhou

    (University of Science and Technology of China)

  • Yuhao Zhang

    (University of Science and Technology of China)

  • Kun Zheng

    (Faculty of Materials and Manufacturing, Beijing University of Technology)

  • Shixun Lian

    (College of Chemistry and Chemical Engineering, Hunan Normal University)

  • Qinghua Liu

    (University of Science and Technology of China)

Abstract

Although the acidic oxygen evolution reaction (OER) plays a crucial role in proton-exchange membrane water electrolysis (PEMWE) devices, challenges remain owing to the lack of efficient and acid-stable electrocatalysts. Herein, we present a low-iridium electrocatalyst in which tensile-strained iridium atoms are localized at manganese-oxide surface cation sites (TS-Ir/MnO2) for high and sustainable OER activity. In situ synchrotron characterizations reveal that the TS-Ir/MnO2 can trigger a continuous localized lattice oxygen-mediated (L-LOM) mechanism. In particular, the L-LOM process could substantially boost the adsorption and transformation of H2O molecules over the oxygen vacancies around the tensile-strained Ir sites and prevent further loss of lattice oxygen atoms in the inner MnO2 bulk to optimize the structural integrity of the catalyst. Importantly, the resultant PEMWE device fabricated using TS-Ir/MnO2 delivers a current density of 500 mA cm−2 and operates stably for 200 h.

Suggested Citation

  • Hui Su & Chenyu Yang & Meihuan Liu & Xu Zhang & Wanlin Zhou & Yuhao Zhang & Kun Zheng & Shixun Lian & Qinghua Liu, 2024. "Tensile straining of iridium sites in manganese oxides for proton-exchange membrane water electrolysers," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-023-44483-6
    DOI: 10.1038/s41467-023-44483-6
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    References listed on IDEAS

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    1. Hui Su & Wanlin Zhou & Wu Zhou & Yuanli Li & Lirong Zheng & Hui Zhang & Meihuan Liu & Xiuxiu Zhang & Xuan Sun & Yanzhi Xu & Fengchun Hu & Jing Zhang & Tiandou Hu & Qinghua Liu & Shiqiang Wei, 2021. "In-situ spectroscopic observation of dynamic-coupling oxygen on atomically dispersed iridium electrocatalyst for acidic water oxidation," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    2. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    3. Rui Li & Haiyun Wang & Fei Hu & K. C. Chan & Xiongjun Liu & Zhaoping Lu & Jing Wang & Zhibin Li & Longjiao Zeng & Yuanyuan Li & Xiaojun Wu & Yujie Xiong, 2021. "IrW nanochannel support enabling ultrastable electrocatalytic oxygen evolution at 2 A cm−2 in acidic media," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    4. Yubo Chen & Haiyan Li & Jingxian Wang & Yonghua Du & Shibo Xi & Yuanmiao Sun & Matthew Sherburne & Joel W. Ager & Adrian C. Fisher & Zhichuan J. Xu, 2019. "Exceptionally active iridium evolved from a pseudo-cubic perovskite for oxygen evolution in acid," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    5. Shunsuke Yagi & Ikuya Yamada & Hirofumi Tsukasaki & Akihiro Seno & Makoto Murakami & Hiroshi Fujii & Hungru Chen & Naoto Umezawa & Hideki Abe & Norimasa Nishiyama & Shigeo Mori, 2015. "Covalency-reinforced oxygen evolution reaction catalyst," Nature Communications, Nature, vol. 6(1), pages 1-6, November.
    6. Xiaopeng Wang & Shibo Xi & Pengru Huang & Yonghua Du & Haoyin Zhong & Qing Wang & Armando Borgna & Yong-Wei Zhang & Zhenbo Wang & Hao Wang & Zhi Gen Yu & Wee Siang Vincent Lee & Junmin Xue, 2022. "Pivotal role of reversible NiO6 geometric conversion in oxygen evolution," Nature, Nature, vol. 611(7937), pages 702-708, November.
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