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Coordination modulation of hydrated zinc ions to enhance redox reversibility of zinc batteries

Author

Listed:
  • Song Chen

    (Shandong University)

  • Deluo Ji

    (Shandong University)

  • Qianwu Chen

    (Shandong University)

  • Jizhen Ma

    (Shandong University)

  • Shaoqi Hou

    (University of Technology Sydney)

  • Jintao Zhang

    (Shandong University)

Abstract

The dendrite growth of zinc and the side reactions including hydrogen evolution often degrade performances of zinc-based batteries. These issues are closely related to the desolvation process of hydrated zinc ions. Here we show that the efficient regulation on the solvation structure and chemical properties of hydrated zinc ions can be achieved by adjusting the coordination micro-environment with zinc phenolsulfonate and tetrabutylammonium 4-toluenesulfonate as a family of electrolytes. The theoretical understanding and in-situ spectroscopy analysis revealed that the favorable coordination of conjugated anions involved in hydrogn bond network minimizes the activate water molecules of hydrated zinc ion, thus improving the zinc/electrolyte interface stability to suppress the dendrite growth and side reactions. With the reversibly cycling of zinc electrode over 2000 h with a low overpotential of 17.7 mV, the full battery with polyaniline cathode demonstrated the impressive cycling stability for 10000 cycles. This work provides inspiring fundamental principles to design advanced electrolytes under the dual contributions of solvation modulation and interface regulation for high-performing zinc-based batteries and others.

Suggested Citation

  • Song Chen & Deluo Ji & Qianwu Chen & Jizhen Ma & Shaoqi Hou & Jintao Zhang, 2023. "Coordination modulation of hydrated zinc ions to enhance redox reversibility of zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39237-3
    DOI: 10.1038/s41467-023-39237-3
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    1. Jingxu Zheng & David C. Bock & Tian Tang & Qing Zhao & Jiefu Yin & Killian R. Tallman & Garrett Wheeler & Xiaotun Liu & Yue Deng & Shuo Jin & Amy C. Marschilok & Esther S. Takeuchi & Kenneth J. Takeuc, 2021. "Regulating electrodeposition morphology in high-capacity aluminium and zinc battery anodes using interfacial metal–substrate bonding," Nature Energy, Nature, vol. 6(4), pages 398-406, April.
    2. Huayu Qiu & Xiaofan Du & Jingwen Zhao & Yantao Wang & Jiangwei Ju & Zheng Chen & Zhenglin Hu & Dongpeng Yan & Xinhong Zhou & Guanglei Cui, 2019. "Zinc anode-compatible in-situ solid electrolyte interphase via cation solvation modulation," Nature Communications, Nature, vol. 10(1), pages 1-12, December.
    3. Dipan Kundu & Brian D. Adams & Victor Duffort & Shahrzad Hosseini Vajargah & Linda F. Nazar, 2016. "A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode," Nature Energy, Nature, vol. 1(10), pages 1-8, October.
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    Cited by:

    1. Zhiyang Zheng & Xiongwei Zhong & Qi Zhang & Mengtian Zhang & Lixin Dai & Xiao Xiao & Jiahe Xu & Miaolun Jiao & Boran Wang & Hong Li & Yeyang Jia & Rui Mao & Guangmin Zhou, 2024. "An extended substrate screening strategy enabling a low lattice mismatch for highly reversible zinc anodes," Nature Communications, Nature, vol. 15(1), pages 1-14, December.

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