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Nano-crumples induced Sn-Bi bimetallic interface pattern with moderate electron bank for highly efficient CO2 electroreduction

Author

Listed:
  • Bohua Ren

    (South China Normal University
    University of Waterloo)

  • Guobin Wen

    (South China Normal University
    University of Waterloo)

  • Rui Gao

    (University of Waterloo)

  • Dan Luo

    (South China Normal University
    University of Waterloo)

  • Zhen Zhang

    (University of Waterloo)

  • Weibin Qiu

    (South China Normal University
    University of Waterloo)

  • Qianyi Ma

    (University of Waterloo)

  • Xin Wang

    (South China Normal University
    South China Normal University)

  • Yi Cui

    (Chinese Academy of Sciences)

  • Luis Ricardez–Sandoval

    (University of Waterloo)

  • Aiping Yu

    (University of Waterloo)

  • Zhongwei Chen

    (University of Waterloo)

Abstract

CO2 electroreduction reaction offers an attractive approach to global carbon neutrality. Industrial CO2 electrolysis towards formate requires stepped-up current densities, which is limited by the difficulty of precisely reconciling the competing intermediates (COOH* and HCOO*). Herein, nano-crumples induced Sn-Bi bimetallic interface-rich materials are in situ designed by tailored electrodeposition under CO2 electrolysis conditions, significantly expediting formate production. Compared with Sn-Bi bulk alloy and pure Sn, this Sn-Bi interface pattern delivers optimum upshift of Sn p-band center, accordingly the moderate valence electron depletion, which leads to weakened Sn-C hybridization of competing COOH* and suitable Sn-O hybridization of HCOO*. Superior partial current density up to 140 mA/cm2 for formate is achieved. High Faradaic efficiency (>90%) is maintained at a wide potential window with a durability of 160 h. In this work, we elevate the interface design of highly active and stable materials for efficient CO2 electroreduction.

Suggested Citation

  • Bohua Ren & Guobin Wen & Rui Gao & Dan Luo & Zhen Zhang & Weibin Qiu & Qianyi Ma & Xin Wang & Yi Cui & Luis Ricardez–Sandoval & Aiping Yu & Zhongwei Chen, 2022. "Nano-crumples induced Sn-Bi bimetallic interface pattern with moderate electron bank for highly efficient CO2 electroreduction," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29861-w
    DOI: 10.1038/s41467-022-29861-w
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    1. Haifeng Shen & Huanyu Jin & Haobo Li & Herui Wang & Jingjing Duan & Yan Jiao & Shi-Zhang Qiao, 2023. "Acidic CO2-to-HCOOH electrolysis with industrial-level current on phase engineered tin sulfide," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

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