IDEAS home Printed from https://ideas.repec.org/a/nat/natene/v1y2016i10d10.1038_nenergy.2016.119.html
   My bibliography  Save this article

A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode

Author

Listed:
  • Dipan Kundu

    (University of Waterloo)

  • Brian D. Adams

    (University of Waterloo)

  • Victor Duffort

    (University of Waterloo)

  • Shahrzad Hosseini Vajargah

    (University of Waterloo)

  • Linda F. Nazar

    (University of Waterloo)

Abstract

Although non-aqueous Li-ion batteries possess significantly higher energy density than their aqueous counterparts, the latter can be more feasible for grid-scale applications when cost, safety and cycle life are taken into consideration. Moreover, aqueous Zn-ion batteries have an energy storage advantage over alkali-based batteries as they can employ Zn metal as the negative electrode, dramatically increasing energy density. However, their development is plagued by a limited choice of positive electrodes, which often show poor rate capability and inadequate cycle life. Here we report a vanadium oxide bronze pillared by interlayer Zn2+ ions and water (Zn0.25V2O5⋅nH2O), as the positive electrode for a Zn cell. A reversible Zn2+ ion (de)intercalation storage process at fast rates, with more than one Zn2+ per formula unit (a capacity up to 300 mAh g−1), is characterized. The Zn cell offers an energy density of ∼450 Wh l−1 and exhibits a capacity retention of more than 80% over 1,000 cycles, with no dendrite formation at the Zn electrode.

Suggested Citation

  • Dipan Kundu & Brian D. Adams & Victor Duffort & Shahrzad Hosseini Vajargah & Linda F. Nazar, 2016. "A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode," Nature Energy, Nature, vol. 1(10), pages 1-8, October.
    • Handle: RePEc:nat:natene:v:1:y:2016:i:10:d:10.1038_nenergy.2016.119
    DOI: 10.1038/nenergy.2016.119
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/nenergy2016119
    File Function: Abstract
    Download Restriction: Access to the full text of the articles in this series is restricted.
    File URL: https://libkey.io/10.1038/nenergy.2016.119?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Yu Wang & Tairan Wang & Shuyu Bu & Jiaxiong Zhu & Yanbo Wang & Rong Zhang & Hu Hong & Wenjun Zhang & Jun Fan & Chunyi Zhi, 2023. "Sulfolane-containing aqueous electrolyte solutions for producing efficient ampere-hour-level zinc metal battery pouch cells," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    2. Songshan Bi & Shuai Wang & Fang Yue & Zhiwei Tie & Zhiqiang Niu, 2021. "A rechargeable aqueous manganese-ion battery based on intercalation chemistry," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    3. Chen, Binbin & Xuan, Jin & Offer, Gregory James & Wang, Huizhi, 2020. "Multiplex measurement of diffusion in zinc battery electrolytes from microfluidics using Raman microspectroscopy," Applied Energy, Elsevier, vol. 279(C).
    4. Yangmoon Kim & Youngbin Park & Minkwan Kim & Jimin Lee & Ki Jae Kim & Jang Wook Choi, 2022. "Corrosion as the origin of limited lifetime of vanadium oxide-based aqueous zinc ion batteries," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    5. Feifei Wang & Jipeng Zhang & Haotian Lu & Hanbing Zhu & Zihui Chen & Lu Wang & Jinyang Yu & Conghui You & Wenhao Li & Jianwei Song & Zhe Weng & Chunpeng Yang & Quan-Hong Yang, 2023. "Production of gas-releasing electrolyte-replenishing Ah-scale zinc metal pouch cells with aqueous gel electrolyte," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    6. Zhiwei Li & Yinghong Xu & Langyuan Wu & Jiaxin Cui & Hui Dou & Xiaogang Zhang, 2023. "Enabling giant thermopower by heterostructure engineering of hydrated vanadium pentoxide for zinc ion thermal charging cells," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    7. Shengmei Chen & Yiran Ying & Longtao Ma & Daming Zhu & Haitao Huang & Li Song & Chunyi Zhi, 2023. "An asymmetric electrolyte to simultaneously meet contradictory requirements of anode and cathode," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    8. Priya Lakshmanan & Subadevi Rengapillai & Sivakumar Marimuthu & Suryanarayanan Vembu, 2022. "Turning Trash to Treasure: Reusable Glucose Kit as a Cell Using ZnO Derived from Metal Organic Framework (MOF) Electrode for Redox Flow Battery," Energies, MDPI, vol. 15(20), pages 1-15, October.
    9. Kefu Zhu & Shiqiang Wei & Hongwei Shou & Feiran Shen & Shuangming Chen & Pengjun Zhang & Changda Wang & Yuyang Cao & Xin Guo & Mi Luo & Hongjun Zhang & Bangjiao Ye & Xiaojun Wu & Lunhua He & Li Song, 2021. "Defect engineering on V2O3 cathode for long-cycling aqueous zinc metal batteries," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    10. Chang Li & Ryan Kingsbury & Arashdeep Singh Thind & Abhinandan Shyamsunder & Timothy T. Fister & Robert F. Klie & Kristin A. Persson & Linda F. Nazar, 2023. "Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    11. Song Chen & Deluo Ji & Qianwu Chen & Jizhen Ma & Shaoqi Hou & Jintao Zhang, 2023. "Coordination modulation of hydrated zinc ions to enhance redox reversibility of zinc batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    12. Yuwei Zhao & Yue Lu & Huiping Li & Yongbin Zhu & You Meng & Na Li & Donghong Wang & Feng Jiang & Funian Mo & Changbai Long & Ying Guo & Xinliang Li & Zhaodong Huang & Qing Li & Johnny C. Ho & Jun Fan , 2022. "Few-layer bismuth selenide cathode for low-temperature quasi-solid-state aqueous zinc metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-12, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natene:v:1:y:2016:i:10:d:10.1038_nenergy.2016.119. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    We have no bibliographic references for this item. You can help adding them by using this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.