IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v14y2023i1d10.1038_s41467-023-38050-2.html
   My bibliography  Save this article

Achieving volatile potassium promoted ammonia synthesis via mechanochemistry

Author

Listed:
  • Jong-Hoon Kim

    (Ulsan National Institute of Science and Technology (UNIST))

  • Tian-Yi Dai

    (Key Laboratory of Automobile Materials (Jilin University), Ministry of Education, and School of Materials Science and Engineering, Jilin University)

  • Mihyun Yang

    (Pohang University of Science and Technology)

  • Jeong-Min Seo

    (Ulsan National Institute of Science and Technology (UNIST))

  • Jae Seong Lee

    (Ulsan National Institute of Science and Technology (UNIST))

  • Do Hyung Kweon

    (Ulsan National Institute of Science and Technology (UNIST))

  • Xing-You Lang

    (Key Laboratory of Automobile Materials (Jilin University), Ministry of Education, and School of Materials Science and Engineering, Jilin University)

  • Kyuwook Ihm

    (Pohang University of Science and Technology)

  • Tae Joo Shin

    (Ulsan National Institute of Science and Technology (UNIST))

  • Gao-Feng Han

    (Ulsan National Institute of Science and Technology (UNIST)
    Key Laboratory of Automobile Materials (Jilin University), Ministry of Education, and School of Materials Science and Engineering, Jilin University)

  • Qing Jiang

    (Key Laboratory of Automobile Materials (Jilin University), Ministry of Education, and School of Materials Science and Engineering, Jilin University)

  • Jong-Beom Baek

    (Ulsan National Institute of Science and Technology (UNIST))

Abstract

Potassium oxide (K2O) is used as a promotor in industrial ammonia synthesis, although metallic potassium (K) is better in theory. The reason K2O is used is because metallic K, which volatilizes around 400 °C, separates from the catalyst in the harsh ammonia synthesis conditions of the Haber-Bosch process. To maximize the efficiency of ammonia synthesis, using metallic K with low temperature reaction below 400 °C is prerequisite. Here, we synthesize ammonia using metallic K and Fe as a catalyst via mechanochemical process near ambient conditions (45 °C, 1 bar). The final ammonia concentration reaches as high as 94.5 vol%, which was extraordinarily higher than that of the Haber-Bosch process (25.0 vol%, 450 °C, 200 bar) and our previous work (82.5 vol%, 45 °C, 1 bar).

Suggested Citation

  • Jong-Hoon Kim & Tian-Yi Dai & Mihyun Yang & Jeong-Min Seo & Jae Seong Lee & Do Hyung Kweon & Xing-You Lang & Kyuwook Ihm & Tae Joo Shin & Gao-Feng Han & Qing Jiang & Jong-Beom Baek, 2023. "Achieving volatile potassium promoted ammonia synthesis via mechanochemistry," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38050-2
    DOI: 10.1038/s41467-023-38050-2
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-023-38050-2
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-023-38050-2?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Tian-Nan Ye & Sang-Won Park & Yangfan Lu & Jiang Li & Masato Sasase & Masaaki Kitano & Tomofumi Tada & Hideo Hosono, 2020. "Vacancy-enabled N2 activation for ammonia synthesis on an Ni-loaded catalyst," Nature, Nature, vol. 583(7816), pages 391-395, July.
    2. Yuya Ashida & Kazuya Arashiba & Kazunari Nakajima & Yoshiaki Nishibayashi, 2019. "Molybdenum-catalysed ammonia production with samarium diiodide and alcohols or water," Nature, Nature, vol. 568(7753), pages 536-540, April.
    3. Suzanne Z. Andersen & Viktor Čolić & Sungeun Yang & Jay A. Schwalbe & Adam C. Nielander & Joshua M. McEnaney & Kasper Enemark-Rasmussen & Jon G. Baker & Aayush R. Singh & Brian A. Rohr & Michael J. St, 2019. "Author Correction: A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements," Nature, Nature, vol. 574(7777), pages 5-5, October.
    4. Suzanne Z. Andersen & Viktor Čolić & Sungeun Yang & Jay A. Schwalbe & Adam C. Nielander & Joshua M. McEnaney & Kasper Enemark-Rasmussen & Jon G. Baker & Aayush R. Singh & Brian A. Rohr & Michael J. St, 2019. "A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements," Nature, Nature, vol. 570(7762), pages 504-508, June.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ziming Wang & Xuanli Dong & Xiao-Fen Li & Yawei Feng & Shunning Li & Wei Tang & Zhong Lin Wang, 2024. "A contact-electro-catalysis process for producing reactive oxygen species by ball milling of triboelectric materials," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    2. Xiong, Chuhao & Wu, Jin & Ji, Zhengang & Wu, Ye & Liu, Dong, 2024. "Unraveling the role of alkali metal in the biochar for enhancing the chemical looping ammonia generation efficiency," Renewable Energy, Elsevier, vol. 220(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Huize Wang & Ranga Rohit Seemakurthi & Gao-Feng Chen & Volker Strauss & Oleksandr Savateev & Guangtong Hai & Liangxin Ding & Núria López & Haihui Wang & Markus Antonietti, 2023. "Laser-induced nitrogen fixation," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    2. Doris Segets & Corina Andronescu & Ulf-Peter Apfel, 2023. "Accelerating CO2 electrochemical conversion towards industrial implementation," Nature Communications, Nature, vol. 14(1), pages 1-5, December.
    3. Xu, Haiyang & Zhang, Le & Wei, ShengJie & Tong, Xuan & Yang, Yue & Ji, Xu, 2024. "A novel solar system for photothermal-assisted electrocatalytic nitrate reduction reaction to ammonia," Renewable Energy, Elsevier, vol. 221(C).
    4. Cheng Du & Joel P. Mills & Asfaw G. Yohannes & Wei Wei & Lei Wang & Siyan Lu & Jian-Xiang Lian & Maoyu Wang & Tao Guo & Xiyang Wang & Hua Zhou & Cheng-Jun Sun & John Z. Wen & Brian Kendall & Martin Co, 2023. "Cascade electrocatalysis via AgCu single-atom alloy and Ag nanoparticles in CO2 electroreduction toward multicarbon products," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    5. Xianbiao Fu & Aoni Xu & Jakob B. Pedersen & Shaofeng Li & Rokas Sažinas & Yuanyuan Zhou & Suzanne Z. Andersen & Mattia Saccoccio & Niklas H. Deissler & Jon Bjarke Valbæk Mygind & Jakob Kibsgaard & Pet, 2024. "Phenol as proton shuttle and buffer for lithium-mediated ammonia electrosynthesis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    6. Po-Wei Huang & Marta C. Hatzell, 2022. "Prospects and good experimental practices for photocatalytic ammonia synthesis," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    7. Paul A. Kempler & Adam C. Nielander, 2023. "Reliable reporting of Faradaic efficiencies for electrocatalysis research," Nature Communications, Nature, vol. 14(1), pages 1-4, December.
    8. Rao, Xufeng & Liu, Minmin & Chien, Meifang & Inoue, Chihiro & Zhang, Jiujun & Liu, Yuyu, 2022. "Recent progress in noble metal electrocatalysts for nitrogen-to-ammonia conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    9. Jia-Yi Fang & Qi-Zheng Zheng & Yao-Yin Lou & Kuang-Min Zhao & Sheng-Nan Hu & Guang Li & Ouardia Akdim & Xiao-Yang Huang & Shi-Gang Sun, 2022. "Ampere-level current density ammonia electrochemical synthesis using CuCo nanosheets simulating nitrite reductase bifunctional nature," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    10. Ang Cao & Vanessa J. Bukas & Vahid Shadravan & Zhenbin Wang & Hao Li & Jakob Kibsgaard & Ib Chorkendorff & Jens K. Nørskov, 2022. "A spin promotion effect in catalytic ammonia synthesis," Nature Communications, Nature, vol. 13(1), pages 1-7, December.
    11. Jie Dai & Yawen Tong & Long Zhao & Zhiwei Hu & Chien-Te Chen & Chang-Yang Kuo & Guangming Zhan & Jiaxian Wang & Xingyue Zou & Qian Zheng & Wei Hou & Ruizhao Wang & Kaiyuan Wang & Rui Zhao & Xiang-Kui , 2024. "Spin polarized Fe1−Ti pairs for highly efficient electroreduction nitrate to ammonia," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    12. Yukio Watanabe & Wataru Aoki & Mitsuyoshi Ueda, 2021. "Sustainable Biological Ammonia Production towards a Carbon-Free Society," Sustainability, MDPI, vol. 13(17), pages 1-13, August.
    13. Fang, Jing & Xiong, Chuhao & Feng, Mingqian & Wu, Ye & Liu, Dong, 2022. "Utilization of carbon-based energy as raw material instead of fuel with low CO2 emissions: Energy analyses and process integration of chemical looping ammonia generation," Applied Energy, Elsevier, vol. 312(C).
    14. Sun, Shangcong & Jiang, Qiuqiao & Zhao, Dongyue & Cao, Tiantian & Sha, Hao & Zhang, Chuankun & Song, Haitao & Da, Zhijian, 2022. "Ammonia as hydrogen carrier: Advances in ammonia decomposition catalysts for promising hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
    15. Chen, Chunchao & Ji, Rui & Xia, Xiaoyong & Jin, Liujun & Deng, Kaiyuan & Xu, Qingfeng & Lu, Jianmei, 2024. "Dispersed Bi2S3 site in a porphyrin-based metal–organic framework for photocatalytic nitrogen fixation," Applied Energy, Elsevier, vol. 357(C).
    16. Mushtaq, Muhammad Asim & Arif, Muhammad & Yasin, Ghulam & Tabish, Mohammad & Kumar, Anuj & Ibraheem, Shumaila & Ye, Wen & Ajmal, Saira & Zhao, Jie & Li, Pengyan & Liu, Jianfang & Saad, Ali & Fang, Xia, 2023. "Recent developments in heterogeneous electrocatalysts for ambient nitrogen reduction to ammonia: Activity, challenges, and future perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 176(C).
    17. Jieyuan Li & Ruimin Chen & Jielin Wang & Ying Zhou & Guidong Yang & Fan Dong, 2022. "Subnanometric alkaline-earth oxide clusters for sustainable nitrate to ammonia photosynthesis," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    18. Wenhui He & Jian Zhang & Stefan Dieckhöfer & Swapnil Varhade & Ann Cathrin Brix & Anna Lielpetere & Sabine Seisel & João R. C. Junqueira & Wolfgang Schuhmann, 2022. "Splicing the active phases of copper/cobalt-based catalysts achieves high-rate tandem electroreduction of nitrate to ammonia," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    19. Pei Xiong & Zhihang Xu & Tai-Sing Wu & Tong Yang & Qiong Lei & Jiangtong Li & Guangchao Li & Ming Yang & Yun-Liang Soo & Robert David Bennett & Shu Ping Lau & Shik Chi Edman Tsang & Ye Zhu & Molly Men, 2024. "Synthesis of core@shell catalysts guided by Tammann temperature," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
    20. Zichuang Li & Yangfan Lu & Jiang Li & Miao Xu & Yanpeng Qi & Sang-Won Park & Masaaki Kitano & Hideo Hosono & Jie-Sheng Chen & Tian-Nan Ye, 2023. "Multiple reaction pathway on alkaline earth imide supported catalysts for efficient ammonia synthesis," Nature Communications, Nature, vol. 14(1), pages 1-12, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38050-2. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.