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Room temperature all-solid-state lithium batteries based on a soluble organic cage ionic conductor

Author

Listed:
  • Jing Li

    (Shenzhen Engineering Lab of Flexible Transparent Conductive Films, School of Materials Science and Engineering, Harbin Institute of Technology
    i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences
    Suzhou University of Science and Technology)

  • Jizhen Qi

    (i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences)

  • Feng Jin

    (i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences)

  • Fengrui Zhang

    (i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences)

  • Lei Zheng

    (i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences)

  • Lingfei Tang

    (i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences)

  • Rong Huang

    (Vacuum Interconnected Nanotech Workstation (Nano-X), Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences)

  • Jingjing Xu

    (i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences)

  • Hongwei Chen

    (Huaqiao University)

  • Ming Liu

    (University of Liverpool)

  • Yejun Qiu

    (Shenzhen Engineering Lab of Flexible Transparent Conductive Films, School of Materials Science and Engineering, Harbin Institute of Technology)

  • Andrew I. Cooper

    (University of Liverpool)

  • Yanbin Shen

    (i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences)

  • Liwei Chen

    (i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO), Chinese Academy of Sciences
    Vacuum Interconnected Nanotech Workstation (Nano-X), Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences
    Shanghai Jiaotong University)

Abstract

All solid-state lithium batteries (SSLBs) are poised to have higher energy density and better safety than current liquid-based Li-ion batteries, but a central requirement is effective ionic conduction pathways throughout the entire cell. Here we develop a catholyte based on an emerging class of porous materials, porous organic cages (POCs). A key feature of these Li+ conducting POCs is their solution-processibility. They can be dissolved in a cathode slurry, which allows the fabrication of solid-state cathodes using the conventional slurry coating method. These Li+ conducting cages recrystallize and grow on the surface of the cathode particles during the coating process and are therefore dispersed uniformly in the slurry-coated cathodes to form a highly effective ion-conducting network. This catholyte is shown to be compatible with cathode active materials such as LiFePO4, LiCoO2 and LiNi0.5Co0.2Mn0.3O2, and results in SSLBs with decent electrochemical performance at room temperature.

Suggested Citation

  • Jing Li & Jizhen Qi & Feng Jin & Fengrui Zhang & Lei Zheng & Lingfei Tang & Rong Huang & Jingjing Xu & Hongwei Chen & Ming Liu & Yejun Qiu & Andrew I. Cooper & Yanbin Shen & Liwei Chen, 2022. "Room temperature all-solid-state lithium batteries based on a soluble organic cage ionic conductor," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29743-1
    DOI: 10.1038/s41467-022-29743-1
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    References listed on IDEAS

    as
    1. Yong-Gun Lee & Satoshi Fujiki & Changhoon Jung & Naoki Suzuki & Nobuyoshi Yashiro & Ryo Omoda & Dong-Su Ko & Tomoyuki Shiratsuchi & Toshinori Sugimoto & Saebom Ryu & Jun Hwan Ku & Taku Watanabe & Youn, 2020. "High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes," Nature Energy, Nature, vol. 5(4), pages 299-308, April.
    2. Ming Liu & Linjiang Chen & Scott Lewis & Samantha Y. Chong & Marc A. Little & Tom Hasell & Iain M. Aldous & Craig M. Brown & Martin W. Smith & Carole A. Morrison & Laurence J. Hardwick & Andrew I. Coo, 2016. "Three-dimensional protonic conductivity in porous organic cage solids," Nature Communications, Nature, vol. 7(1), pages 1-9, November.
    3. Simon Randau & Dominik A. Weber & Olaf Kötz & Raimund Koerver & Philipp Braun & André Weber & Ellen Ivers-Tiffée & Torben Adermann & Jörn Kulisch & Wolfgang G. Zeier & Felix H. Richter & Jürgen Janek, 2020. "Benchmarking the performance of all-solid-state lithium batteries," Nature Energy, Nature, vol. 5(3), pages 259-270, March.
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