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Realizing long-cycling all-solid-state Li-In||TiS2 batteries using Li6+xMxAs1-xS5I (M=Si, Sn) sulfide solid electrolytes

Author

Listed:
  • Pushun Lu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Yu Xia

    (Beijing ByteDance Technology Co Ltd)

  • Guochen Sun

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Dengxu Wu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Siyuan Wu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Wenlin Yan

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Xiang Zhu

    (University of Science and Technology of China
    Tianmu Lake Institute of Advanced Energy Storage Technologies)

  • Jiaze Lu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences)

  • Quanhai Niu

    (Tianmu Lake Institute of Advanced Energy Storage Technologies)

  • Shaochen Shi

    (Beijing ByteDance Technology Co Ltd)

  • Zhengju Sha

    (Beijing ByteDance Technology Co Ltd)

  • Liquan Chen

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences
    Tianmu Lake Institute of Advanced Energy Storage Technologies
    Yangtze River Delta Physics Research Center)

  • Hong Li

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences
    University of Science and Technology of China
    Tianmu Lake Institute of Advanced Energy Storage Technologies)

  • Fan Wu

    (Chinese Academy of Sciences
    University of Chinese Academy of Sciences
    University of Science and Technology of China
    Tianmu Lake Institute of Advanced Energy Storage Technologies)

Abstract

Inorganic sulfide solid-state electrolytes, especially Li6PS5X (X = Cl, Br, I), are considered viable materials for developing all-solid-state batteries because of their high ionic conductivity and low cost. However, this class of solid-state electrolytes suffers from structural and chemical instability in humid air environments and a lack of compatibility with layered oxide positive electrode active materials. To circumvent these issues, here, we propose Li6+xMxAs1-xS5I (M=Si, Sn) as sulfide solid electrolytes. When the Li6+xSixAs1-xS5I (x = 0.8) is tested in combination with a Li-In negative electrode and Ti2S-based positive electrode at 30 °C and 30 MPa, the Li-ion lab-scale Swagelok cells demonstrate long cycle life of almost 62500 cycles at 2.44 mA cm−2, decent power performance (up to 24.45 mA cm−2) and areal capacity of 9.26 mAh cm−2 at 0.53 mA cm−2.

Suggested Citation

  • Pushun Lu & Yu Xia & Guochen Sun & Dengxu Wu & Siyuan Wu & Wenlin Yan & Xiang Zhu & Jiaze Lu & Quanhai Niu & Shaochen Shi & Zhengju Sha & Liquan Chen & Hong Li & Fan Wu, 2023. "Realizing long-cycling all-solid-state Li-In||TiS2 batteries using Li6+xMxAs1-xS5I (M=Si, Sn) sulfide solid electrolytes," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-39686-w
    DOI: 10.1038/s41467-023-39686-w
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    References listed on IDEAS

    as
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    4. Xingfeng He & Yizhou Zhu & Yifei Mo, 2017. "Origin of fast ion diffusion in super-ionic conductors," Nature Communications, Nature, vol. 8(1), pages 1-7, August.
    5. Luhan Ye & Xin Li, 2021. "A dynamic stability design strategy for lithium metal solid state batteries," Nature, Nature, vol. 593(7858), pages 218-222, May.
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