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Boosting lithium ion conductivity of antiperovskite solid electrolyte by potassium ions substitution for cation clusters

Author

Listed:
  • Lei Gao

    (Peking University)

  • Xinyu Zhang

    (Southern University of Science and Technology)

  • Jinlong Zhu

    (Southern University of Science and Technology)

  • Songbai Han

    (Southern University of Science and Technology)

  • Hao Zhang

    (Peking University)

  • Liping Wang

    (Southern University of Science and Technology)

  • Ruo Zhao

    (Southern University of Science and Technology)

  • Song Gao

    (Peking University)

  • Shuai Li

    (Southern University of Science and Technology)

  • Yonggang Wang

    (Peking University)

  • Dubin Huang

    (Peking University)

  • Yusheng Zhao

    (Southern University of Science and Technology)

  • Ruqiang Zou

    (Peking University)

Abstract

Solid-state electrolytes with high ionic conductivities are crucial for the development of all-solid-state lithium batteries, and there is a strong correlation between the ionic conductivities and underlying lattice structures of solid-state electrolytes. Here, we report a lattice manipulation method of replacing [Li2OH]+ clusters with potassium ions in antiperovskite solid-state electrolyte (Li2OH)0.99K0.01Cl, which leads to a remarkable increase in ionic conductivity (4.5 × 10‒3 mS cm‒1, 25 °C). Mechanistic analysis indicates that the lattice manipulation method leads to the stabilization of the cubic phase and lattice contraction for the antiperovskite, and causes significant changes in Li-ion transport trajectories and migration barriers. Also, the Li||LiFePO4 all-solid-state battery (excess Li and loading of 1.78 mg cm‒2 for LiFePO4) employing (Li2OH)0.99K0.01Cl electrolyte delivers a specific capacity of 116.4 mAh g‒1 at the 150th cycle with a capacity retention of 96.1% at 80 mA g‒1 and 120 °C, which indicates potential application prospects of antiperovskite electrolyte in all-solid-state lithium batteries.

Suggested Citation

  • Lei Gao & Xinyu Zhang & Jinlong Zhu & Songbai Han & Hao Zhang & Liping Wang & Ruo Zhao & Song Gao & Shuai Li & Yonggang Wang & Dubin Huang & Yusheng Zhao & Ruqiang Zou, 2023. "Boosting lithium ion conductivity of antiperovskite solid electrolyte by potassium ions substitution for cation clusters," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-42385-1
    DOI: 10.1038/s41467-023-42385-1
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    References listed on IDEAS

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