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Tribo-electrochemistry induced artificial solid electrolyte interface by self-catalysis

Author

Listed:
  • Chichu Qin

    (Hunan University)

  • Dong Wang

    (Hunan University)

  • Yumin Liu

    (Hunan University)

  • Pengkun Yang

    (Hunan University)

  • Tian Xie

    (Hunan University)

  • Lu Huang

    (Hunan University)

  • Haiyan Zou

    (Hunan University)

  • Guanwu Li

    (Hunan University)

  • Yingpeng Wu

    (Hunan University)

Abstract

Potassium (K) metal is a promising alkali metal anode for its high abundance. However, dendrite on K anode is a serious problem which is even worse than Li. Artificial SEI (ASEI) is one of effective routes for suppressing dendrite. However, there are still some issues of the ASEI made by the traditional methods, e.g. weak adhesion, insufficient/uneven reaction, which deeply affects the ionic diffusion kinetics and the effect of inhibiting dendrites. Herein, through a unique self-catalysis tribo-electrochemistry reaction, a continuous and compact protective layer is successfully constructed on K metal anode in seconds. Such a continuous and compact protective layer can not only improve the K+ diffusion kinetics, but also strongly suppress K dendrite formation by its hard mechanical properties derived from rigid carbon system, as well as the improved K+ conductivity and lowered electronic conductivity from the amorphous KF. As a result, the potassium symmetric cells exhibit stable cycles last more than 1000 h, which is almost 500 times that of pristine K.

Suggested Citation

  • Chichu Qin & Dong Wang & Yumin Liu & Pengkun Yang & Tian Xie & Lu Huang & Haiyan Zou & Guanwu Li & Yingpeng Wu, 2021. "Tribo-electrochemistry induced artificial solid electrolyte interface by self-catalysis," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-27494-z
    DOI: 10.1038/s41467-021-27494-z
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    References listed on IDEAS

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    1. Zhaofeng Wang & Ana G. Herraiz & Ana M. del Hoyo & Marcos G. Suero, 2018. "Generating carbyne equivalents with photoredox catalysis," Nature, Nature, vol. 554(7690), pages 86-91, February.
    2. Wanghuai Xu & Huanxi Zheng & Yuan Liu & Xiaofeng Zhou & Chao Zhang & Yuxin Song & Xu Deng & Michael Leung & Zhengbao Yang & Ronald X. Xu & Zhong Lin Wang & Xiao Cheng Zeng & Zuankai Wang, 2020. "A droplet-based electricity generator with high instantaneous power density," Nature, Nature, vol. 578(7795), pages 392-396, February.
    3. Ji Chen & Xiulin Fan & Qin Li & Hongbin Yang & M. Reza Khoshi & Yaobin Xu & Sooyeon Hwang & Long Chen & Xiao Ji & Chongyin Yang & Huixin He & Chongmin Wang & Eric Garfunkel & Dong Su & Oleg Borodin & , 2020. "Electrolyte design for LiF-rich solid–electrolyte interfaces to enable high-performance microsized alloy anodes for batteries," Nature Energy, Nature, vol. 5(5), pages 386-397, May.
    4. Xiao Liang & Quan Pang & Ivan R. Kochetkov & Marina Safont Sempere & He Huang & Xiaoqi Sun & Linda F. Nazar, 2017. "A facile surface chemistry route to a stabilized lithium metal anode," Nature Energy, Nature, vol. 2(9), pages 1-7, September.
    5. Haiyang Zou & Ying Zhang & Litong Guo & Peihong Wang & Xu He & Guozhang Dai & Haiwu Zheng & Chaoyu Chen & Aurelia Chi Wang & Cheng Xu & Zhong Lin Wang, 2019. "Quantifying the triboelectric series," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
    6. Leqing Deng & Jiale Qu & Xiaogang Niu & Juzhe Liu & Juan Zhang & Youran Hong & Meiying Feng & Jiangwei Wang & Miao Hu & Liang Zeng & Qianfan Zhang & Lin Guo & Yujie Zhu, 2021. "Defect-free potassium manganese hexacyanoferrate cathode material for high-performance potassium-ion batteries," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
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