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Selective Mechanisms of WO 3 Catalyzing CO 2 Desorption and Inhibiting NH 3 Escape

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  • Fengming Chu

    (College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China)

  • Xi Liu

    (College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China)

  • Qianhong Gao

    (College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China)

  • Longchun Zhong

    (Key Laboratory of Cleaner Production and Integrated Resource Utilization of China National Light Industry, Beijing Technology and Business University, Beijing 100048, China)

  • Guozhen Xiao

    (College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
    Shandong GRINM RS Semiconductor Materials Co., Ltd., Dezhou 253084, China)

  • Qianlin Wang

    (College of Mechanical and Electrical Engineering, Beijing University of Chemical Technology, Beijing 100029, China)

Abstract

The high regeneration energy consumption and ammonia escape in the ammonia regeneration process are regarded as the main barriers for the commercial application of CO 2 capture technology based on ammonia solutions. Metal oxides can enhance the CO 2 desorption process and inhibit the ammonia escape at the same time, which can reduce the energy consumption of CO 2 capture systems. Both ammonium carbamate (NH 2 COONH 4 ) and ammonium bicarbonate (NH 4 HCO 3 ) are examined as the rich ammonia solution. The results show that when the concentration of tungsten trioxide (WO 3 ) was 0.1 mol/L, the CO 2 desorption efficiency could be promoted by 18.8% and the ammonia escape efficiency could be reduced about 14%. The mechanism by which WO 3 increased the CO 2 desorption process was clarified by XRD analysis as the production of ammonium tungstate. In addition, the other nine metal oxides exert no catalytic influence on the regeneration process.

Suggested Citation

  • Fengming Chu & Xi Liu & Qianhong Gao & Longchun Zhong & Guozhen Xiao & Qianlin Wang, 2023. "Selective Mechanisms of WO 3 Catalyzing CO 2 Desorption and Inhibiting NH 3 Escape," Sustainability, MDPI, vol. 15(17), pages 1-9, August.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:17:p:13044-:d:1228470
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    References listed on IDEAS

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    2. Cheng, Chin-hung & Li, Kangkang & Yu, Hai & Jiang, Kaiqi & Chen, Jian & Feron, Paul, 2018. "Amine-based post-combustion CO2 capture mediated by metal ions: Advancement of CO2 desorption using copper ions," Applied Energy, Elsevier, vol. 211(C), pages 1030-1038.
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