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A Counter-Current Heat-Exchange Reactor for the Thermal Stimulation of Hydrate-Bearing Sediments

Author

Listed:
  • Judith M. Schicks

    (Helmholtz Centre Potsdam GFZ German Research Centre for Geosciences Section 4.2, Telegrafenberg, Potsdam 14473, Germany)

  • Erik Spangenberg

    (Helmholtz Centre Potsdam GFZ German Research Centre for Geosciences Section 4.2, Telegrafenberg, Potsdam 14473, Germany)

  • Ronny Giese

    (Helmholtz Centre Potsdam GFZ German Research Centre for Geosciences Section 4.2, Telegrafenberg, Potsdam 14473, Germany)

  • Manja Luzi-Helbing

    (Helmholtz Centre Potsdam GFZ German Research Centre for Geosciences Section 4.2, Telegrafenberg, Potsdam 14473, Germany)

  • Mike Priegnitz

    (Helmholtz Centre Potsdam GFZ German Research Centre for Geosciences Section 4.2, Telegrafenberg, Potsdam 14473, Germany)

  • Bettina Beeskow-Strauch

    (Helmholtz Centre Potsdam GFZ German Research Centre for Geosciences Section 4.2, Telegrafenberg, Potsdam 14473, Germany)

Abstract

Since huge amounts of CH 4 are bound in natural gas hydrates occurring at active and passive continental margins and in permafrost regions, the production of natural gas from hydrate-bearing sediments has become of more and more interest. Three different methods to destabilize hydrates and release the CH 4 gas are discussed in principle: thermal stimulation, depressurization and chemical stimulation. This study focusses on the thermal stimulation using a counter-current heat-exchange reactor for the in situ combustion of CH 4 . The principle of in situ combustion as a method for thermal stimulation of hydrate bearing sediments has been introduced and discussed earlier [1,2]. In this study we present the first results of several tests performed in a pilot plant scale using a counter-current heat-exchange reactor. The heat of the flameless, catalytic oxidation of CH 4 was used for the decomposition of hydrates in sand within a LArge Reservoir Simulator (LARS). Different catalysts were tested, varying from diverse elements of the platinum group to a universal metal catalyst. The results show differences regarding the conversion rate of CH 4 to CO 2 . The promising results of the latest reactor test, for which LARS was filled with sand and ca. 80% of the pore space was saturated with CH 4 hydrate, are also presented in this study. The data analysis showed that about 15% of the CH 4 gas released from hydrates would have to be used for the successful dissociation of all hydrates in the sediment using thermal stimulation via in situ combustion.

Suggested Citation

  • Judith M. Schicks & Erik Spangenberg & Ronny Giese & Manja Luzi-Helbing & Mike Priegnitz & Bettina Beeskow-Strauch, 2013. "A Counter-Current Heat-Exchange Reactor for the Thermal Stimulation of Hydrate-Bearing Sediments," Energies, MDPI, vol. 6(6), pages 1-15, June.
    • Handle: RePEc:gam:jeners:v:6:y:2013:i:6:p:3002-3016:d:26513
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    References listed on IDEAS

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    1. Judith M. Schicks & Erik Spangenberg & Ronny Giese & Bernd Steinhauer & Jens Klump & Manja Luzi, 2011. "New Approaches for the Production of Hydrocarbons from Hydrate Bearing Sediments," Energies, MDPI, vol. 4(1), pages 1-22, January.
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    Cited by:

    1. Olga Gaidukova & Sergey Misyura & Vladimir Morozov & Pavel Strizhak, 2023. "Gas Hydrates: Applications and Advantages," Energies, MDPI, vol. 16(6), pages 1-19, March.
    2. Zhao, Jiafei & Fan, Zhen & Wang, Bin & Dong, Hongsheng & Liu, Yu & Song, Yongchen, 2016. "Simulation of microwave stimulation for the production of gas from methane hydrate sediment," Applied Energy, Elsevier, vol. 168(C), pages 25-37.
    3. Cui, Gan & Dong, Zengrui & Wang, Shun & Xing, Xiao & Shan, Tianxiang & Li, Zili, 2020. "Effect of the water on the flame characteristics of methane hydrate combustion," Applied Energy, Elsevier, vol. 259(C).
    4. Yun-Pei Liang & Shu Liu & Qing-Cui Wan & Bo Li & Hang Liu & Xiao Han, 2018. "Comparison and Optimization of Methane Hydrate Production Process Using Different Methods in a Single Vertical Well," Energies, MDPI, vol. 12(1), pages 1-21, December.
    5. Bettina Beeskow-Strauch & Judith Maria Schicks & Martin Zimmer, 2015. "Evaluation of CH 4 Gas Permeation Rates through Silicone Membranes and Its Possible Use as CH 4 -Extractor in Gas Hydrate Deposits," Energies, MDPI, vol. 8(6), pages 1-17, June.
    6. Wang, Yi & Feng, Jing-Chun & Li, Xiao-Sen & Zhang, Yu, 2018. "Influence of well pattern on gas recovery from methane hydrate reservoir by large scale experimental investigation," Energy, Elsevier, vol. 152(C), pages 34-45.
    7. Wang, Bin & Dong, Hongsheng & Liu, Yanzhen & Lv, Xin & Liu, Yu & Zhao, Jiafei & Song, Yongchen, 2018. "Evaluation of thermal stimulation on gas production from depressurized methane hydrate deposits☆," Applied Energy, Elsevier, vol. 227(C), pages 710-718.
    8. Wang, Yi & Feng, Jing-Chun & Li, Xiao-Sen & Zhang, Yu, 2017. "Experimental investigation of optimization of well spacing for gas recovery from methane hydrate reservoir in sandy sediment by heat stimulation," Applied Energy, Elsevier, vol. 207(C), pages 562-572.
    9. Yu, Tao & Guan, Guoqing & Abudula, Abuliti & Yoshida, Akihiro & Wang, Dayong & Song, Yongchen, 2019. "Gas recovery enhancement from methane hydrate reservoir in the Nankai Trough using vertical wells," Energy, Elsevier, vol. 166(C), pages 834-844.
    10. Olga Gaidukova & Sergei Misyura & Pavel Strizhak, 2022. "Key Areas of Gas Hydrates Study: Review," Energies, MDPI, vol. 15(5), pages 1-18, February.
    11. Li, Gang & Wu, Dan-Mei & Li, Xiao-Sen & Lv, Qiu-Nan & Li, Chao & Zhang, Yu, 2017. "Experimental measurement and mathematical model of permeability with methane hydrate in quartz sands," Applied Energy, Elsevier, vol. 202(C), pages 282-292.
    12. Xiang-Ru Chen & Xiao-Sen Li & Zhao-Yang Chen & Yu Zhang & Ke-Feng Yan & Qiu-Nan Lv, 2015. "Experimental Investigation into the Combustion Characteristics of Propane Hydrates in Porous Media," Energies, MDPI, vol. 8(2), pages 1-14, February.
    13. Zhen Li & Erik Spangenberg & Judith M. Schicks & Thomas Kempka, 2022. "Numerical Simulation of Hydrate Formation in the LArge-Scale Reservoir Simulator (LARS)," Energies, MDPI, vol. 15(6), pages 1-27, March.
    14. Yun-Pei Liang & Xiao-Sen Li & Bo Li, 2015. "Assessment of Gas Production Potential from Hydrate Reservoir in Qilian Mountain Permafrost Using Five-Spot Horizontal Well System," Energies, MDPI, vol. 8(10), pages 1-22, September.
    15. Lee, Yohan & Kim, Yunju & Lee, Jaehyoung & Lee, Huen & Seo, Yongwon, 2015. "CH4 recovery and CO2 sequestration using flue gas in natural gas hydrates as revealed by a micro-differential scanning calorimeter," Applied Energy, Elsevier, vol. 150(C), pages 120-127.
    16. Yiwei Wang & Yuan Wang & Sunhua Deng & Qiang Li & Jingjing Gu & Haoche Shui & Wei Guo, 2022. "Numerical Simulation Analysis of Heating Effect of Downhole Methane Catalytic Combustion Heater under High Pressure," Energies, MDPI, vol. 15(3), pages 1-23, February.
    17. Wang, Yi & Pan, Mengdi & Mayanna, Sathish & Schleicher, Anja M. & Spangenberg, Erik & Schicks, Judith M., 2020. "Reservoir formation damage during hydrate dissociation in sand-clay sediment from Qilian Mountain permafrost, China," Applied Energy, Elsevier, vol. 263(C).
    18. Li, Xiao-Sen & Xu, Chun-Gang & Zhang, Yu & Ruan, Xu-Ke & Li, Gang & Wang, Yi, 2016. "Investigation into gas production from natural gas hydrate: A review," Applied Energy, Elsevier, vol. 172(C), pages 286-322.
    19. Wang, Yi & Feng, Jing-Chun & Li, Xiao-Sen & Zhang, Yu, 2016. "Experimental and modeling analyses of scaling criteria for methane hydrate dissociation in sediment by depressurization," Applied Energy, Elsevier, vol. 181(C), pages 299-309.
    20. Chen, Bingbing & Sun, Huiru & Zhou, Hang & Yang, Mingjun & Wang, Dayong, 2019. "Effects of pressure and sea water flow on natural gas hydrate production characteristics in marine sediment," Applied Energy, Elsevier, vol. 238(C), pages 274-283.
    21. Li, Bo & Liang, Yun-Pei & Li, Xiao-Sen & Zhou, Lei, 2016. "A pilot-scale study of gas production from hydrate deposits with two-spot horizontal well system," Applied Energy, Elsevier, vol. 176(C), pages 12-21.
    22. Mengdi Pan & Nur Aminatulmimi Ismail & Manja Luzi-Helbing & Carolyn A. Koh & Judith M. Schicks, 2020. "New Insights on a µm-Scale into the Transformation Process of CH 4 Hydrates to CO 2 -Rich Mixed Hydrates," Energies, MDPI, vol. 13(22), pages 1-23, November.

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