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Implementation of Transition Metal Phosphides as Pt-Free Catalysts for PEM Water Electrolysis

Author

Listed:
  • João Brito

    (Laboratory of Separation and Reaction Engineering-Laboratory of Catalysis and Materials (LSRE-LCM), Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias s/n, 4200-465 Porto, Portugal
    Transport Phenomena Research Center (CEFT), Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias s/n, 4200-465 Porto, Portugal
    ALiCE—Associate Laboratory in Chemical Engineering, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal)

  • João Restivo

    (Laboratory of Separation and Reaction Engineering-Laboratory of Catalysis and Materials (LSRE-LCM), Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias s/n, 4200-465 Porto, Portugal
    ALiCE—Associate Laboratory in Chemical Engineering, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal)

  • Juliana P. S. Sousa

    (International Iberian Nanotechnology Laboratory (INL), Avenida Mestre José Veiga, 4715-330 Braga, Portugal)

  • Natalia C. M. Spera

    (International Iberian Nanotechnology Laboratory (INL), Avenida Mestre José Veiga, 4715-330 Braga, Portugal)

  • D. S. Falcão

    (Transport Phenomena Research Center (CEFT), Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias s/n, 4200-465 Porto, Portugal
    ALiCE—Associate Laboratory in Chemical Engineering, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal)

  • Amadeu Rocha

    (Transport Phenomena Research Center (CEFT), Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias s/n, 4200-465 Porto, Portugal
    ALiCE—Associate Laboratory in Chemical Engineering, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal)

  • A. M. F. R. Pinto

    (Transport Phenomena Research Center (CEFT), Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias s/n, 4200-465 Porto, Portugal
    ALiCE—Associate Laboratory in Chemical Engineering, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal)

  • Manuel Fernando R. Pereira

    (Laboratory of Separation and Reaction Engineering-Laboratory of Catalysis and Materials (LSRE-LCM), Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias s/n, 4200-465 Porto, Portugal
    ALiCE—Associate Laboratory in Chemical Engineering, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal)

  • Olívia Salomé G. P. Soares

    (Laboratory of Separation and Reaction Engineering-Laboratory of Catalysis and Materials (LSRE-LCM), Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias s/n, 4200-465 Porto, Portugal
    ALiCE—Associate Laboratory in Chemical Engineering, Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, 4200-465 Porto, Portugal)

Abstract

Proton Exchange Membrane (PEM) water electrolysis (WE) produces H 2 with a high degree of purity, requiring only water and energy. If the energy is provided from renewable energy sources, it releases “Green H 2 ”, a CO 2 -free H 2 . PEMWE uses expensive and rare noble metal catalysts, which hinder their use at a large industrial scale. In this work, the electrocatalytic properties of Transition Metal Phosphides (TMP) catalysts supported on Carbon Black (CB) for Hydrogen Evolution Reaction (HER) were investigated as an alternative to Platinum Group Metals. The physico-chemical properties and catalytic performance of the synthesized catalysts were characterized. In the ex situ experiments, the 25% FeP/CB, 50% FeP/CB and 50% CoP/CB with overpotentials of −156.0, −165.9 and −158.5 mV for a current density of 100 mA cm −2 showed the best catalytic properties, thereby progressing to the PEMWE tests. In those tests, the 50% FeP/CB required an overpotential of 252 mV for a current density of 10 mA cm −2 , quite close to the 220 mV of the Pt catalyst. This work provides a proper approach to the synthesis and characterization of TMP supported on carbon materials for the HER, paving the way for further research in order to replace the currently used PGM in PEMWE.

Suggested Citation

  • João Brito & João Restivo & Juliana P. S. Sousa & Natalia C. M. Spera & D. S. Falcão & Amadeu Rocha & A. M. F. R. Pinto & Manuel Fernando R. Pereira & Olívia Salomé G. P. Soares, 2022. "Implementation of Transition Metal Phosphides as Pt-Free Catalysts for PEM Water Electrolysis," Energies, MDPI, vol. 15(5), pages 1-18, March.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:5:p:1821-:d:762029
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    References listed on IDEAS

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    1. Hughes, J.P. & Clipsham, J. & Chavushoglu, H. & Rowley-Neale, S.J. & Banks, C.E., 2021. "Polymer electrolyte electrolysis: A review of the activity and stability of non-precious metal hydrogen evolution reaction and oxygen evolution reaction catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    2. Nikolaidis, Pavlos & Poullikkas, Andreas, 2017. "A comparative overview of hydrogen production processes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 597-611.
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    1. Cheng Wang & Yibo Wang & Zhaoping Shi & Wenhua Luo & Junjie Ge & Wei Xing & Ge Sang & Changpeng Liu, 2022. "RuCo Alloy Nanoparticles Embedded into N-Doped Carbon for High Efficiency Hydrogen Evolution Electrocatalyst," Energies, MDPI, vol. 15(8), pages 1-13, April.

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