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Experimental Optimization with the Emphasis on Techno-Economic Analysis of Production and Purification of High Value-Added Bioethanol from Sustainable Corn Stover

Author

Listed:
  • Sara E. AbdElhafez

    (Fabrication Technology Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Tarek Taha

    (Environmental Biotechnology Department, Genetic Engineering and Biotechnology Research Institute (GEBRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Ahmed E. Mansy

    (Environment and Natural Materials Research Institute (ENMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Eman El-Desouky

    (Chemistry Department, Faculty of Science, Alexandria University, Ibrahimia 21321, Alexandria, Egypt)

  • Mohamed A. Abu-Saied

    (Polymeric Materials Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Khloud Eltaher

    (Chemistry Department, Faculty of Science, Alexandria University, Ibrahimia 21321, Alexandria, Egypt)

  • Ali Hamdy

    (Environmental Biotechnology Department, Genetic Engineering and Biotechnology Research Institute (GEBRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Gomaa El Fawal

    (Polymeric Materials Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Amr Gamal

    (Physics Department, Faculty of Science, Alexandria University, Moharam Bek 21568, Alexandria, Egypt)

  • Aly M. Hashim

    (Central Laboratory, City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Abdallah S. Elgharbawy

    (Materials Science Department, Institute of Graduate Studies and Research (IGSR), Alexandria University, Shatby 21526, Alexandria, Egypt
    The Egyptian Ethylene and Derivatives Company (ETHYDCO), Ameriya 23511, Alexandria, Egypt)

  • Mona M. Abd El-Latif

    (Fabrication Technology Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

  • Hesham Hamad

    (Fabrication Technology Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt
    Faculty of Chemistry, University of Warsaw, Pasteur 1, 02-093 Warsaw, Poland)

  • Rehab M. Ali

    (Fabrication Technology Research Department, Advanced Technology and New Materials Research Institute (ATNMRI), City of Scientific Research and Technological Applications (SRTA-City), New Borg El-Arab City 21934, Alexandria, Egypt)

Abstract

Bioethanol-derived biomass is a green sustainable source of energy that is highly recommended as an efficient alternative to the replacement of fossil fuels. However, this type of bioethanol production is always expensive with very low bioethanol concentration. Therefore, this work aims to represent a facile and green approach for bioethanol production with high concentration and purity as well as reasonable cost from corn stover (CS). The goal of this study is to characterize CS and its treated samples with maleic acid (CSM) using various characterization analyses, such as proximate and ultimate analysis, HHV, TGA, FTIR, SEM, and CHNS. The bioethanol production stages: Pretreatment, enzymatic degradation, fermentation, and finally bioethanol separation and purification via the pervaporation process, which have been investigated and optimized are associated with the economic analysis. The optimum operating condition of the pretreatment process was 2% maleic acid, 1:20 solid-to-liquid ratio at 45 psi, 120 °C, and 1 h of operation in the autoclave. This process contributes to 53 and 45% lignin and hemicellulose removal, 98% cellulose recovery, and a glucose yield of 741 mg/dL. The yeast isolate succeeded in the production of 1230 mg/dL of bioethanol. This isolated yeast strain was close to Pichia nakasei with a similarity of 98%, and its amplified 18S rRNA gene sequence was deposited in GenBank with the accession number MZ675535. Poly (MMA- co -MA) membrane was synthesized, characterized, and its efficiency for increasing the bioethanol concentration was evaluated using the integrated pervaporation technique. The techno-economic analysis is presented in detail to evaluate the process profitability, which achieves a considerable profit for the whole duration of the project without any losses as it reaches a net profit of USD 1 million in 2023, reaching USD 2.1 million in 2047 for a company with a capacity of 32 thousand tons per year. The sequential strategy offers a promising approach for efficient bioethanol production under mild and environmentally friendly conditions that enable its implication industrially.

Suggested Citation

  • Sara E. AbdElhafez & Tarek Taha & Ahmed E. Mansy & Eman El-Desouky & Mohamed A. Abu-Saied & Khloud Eltaher & Ali Hamdy & Gomaa El Fawal & Amr Gamal & Aly M. Hashim & Abdallah S. Elgharbawy & Mona M. A, 2022. "Experimental Optimization with the Emphasis on Techno-Economic Analysis of Production and Purification of High Value-Added Bioethanol from Sustainable Corn Stover," Energies, MDPI, vol. 15(17), pages 1-33, August.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:17:p:6131-:d:895883
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    References listed on IDEAS

    as
    1. Campbell, Robert M. & Anderson, Nathaniel M. & Daugaard, Daren E. & Naughton, Helen T., 2018. "Financial viability of biofuel and biochar production from forest biomass in the face of market price volatility and uncertainty," Applied Energy, Elsevier, vol. 230(C), pages 330-343.
    2. Yusuf, Abdulfatah Abdu & Inambao, Freddie L., 2020. "Characterization of Ugandan biomass wastes as the potential candidates towards bioenergy production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 117(C).
    3. Singh, Yengkhom Disco & Mahanta, Pinakeswar & Bora, Utpal, 2017. "Comprehensive characterization of lignocellulosic biomass through proximate, ultimate and compositional analysis for bioenergy production," Renewable Energy, Elsevier, vol. 103(C), pages 490-500.
    4. Behera, Shuvashish & Arora, Richa & Nandhagopal, N. & Kumar, Sachin, 2014. "Importance of chemical pretreatment for bioconversion of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 91-106.
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    Cited by:

    1. Nasib Qureshi & Xiaoqing Lin & Shunhui Tao & Siqing Liu & Haibo Huang & Nancy N. Nichols, 2023. "Can Xylose Be Fermented to Biofuel Butanol in Continuous Long-Term Reactors: If Not, What Options Are There?," Energies, MDPI, vol. 16(13), pages 1-21, June.
    2. Elsagan, Zahwa A. & Ali, Rehab M. & El-Naggar, Mohamed A. & El-Ashtoukhy, E.-S.Z. & AbdElhafez, Sara E., 2023. "New perspectives for maximizing sustainable bioethanol production from corn stover," Renewable Energy, Elsevier, vol. 209(C), pages 608-618.

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