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Thermogravimetric and Kinetic Analysis of High-Temperature Thermal Conversion of Pine Wood Sawdust under CO 2 /Ar

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  • Bao Wang

    (State Key Laboratory of Refractories & Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
    Key Laboratory of Ferrous Metallurgy and Resources Utilization, Ministry of Education, Wuhan University of Science and Technology, Wuhan 430081, China)

  • Yujie Li

    (State Key Laboratory of Refractories & Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China)

  • Jianan Zhou

    (State Key Laboratory of Refractories & Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
    Key Laboratory of Ferrous Metallurgy and Resources Utilization, Ministry of Education, Wuhan University of Science and Technology, Wuhan 430081, China)

  • Yi Wang

    (State Key Laboratory of Refractories & Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China)

  • Xun Tao

    (State Key Laboratory of Refractories & Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China)

  • Xiang Zhang

    (State Key Laboratory of Refractories & Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China)

  • Weiming Song

    (State Key Laboratory of Refractories & Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China)

Abstract

The gasification behavior of pine wood sawdust was investigated in CO 2 with different heating rates of 5, 10, 15, and 20 °C/min from room temperature to 1400 °C by thermogravimetric analysis (TGA) and mass spectrometry (MS). It was also examined under Ar to compare the differences observed under CO 2 at heating rate of 10 °C/min. Kinetics of pine wood sawdust thermal decomposition was determined by the models of FWO, KAS and master plot method. TGA results revealed different reaction sections from pyrolysis to char gasification under CO 2 . The pyrolysis behavior was similar under CO 2 and Ar and had a similar energy required value about 590 kJ/kg from 250 °C to 420 °C. CO, CH 4 , and H 2 were the primary gases obtained from thermal decomposition, and the amounts of which in CO 2 atmosphere were higher than those obtained in Ar. The average activation energy for pyrolysis under CO 2 was 184.72 kJ/mol.

Suggested Citation

  • Bao Wang & Yujie Li & Jianan Zhou & Yi Wang & Xun Tao & Xiang Zhang & Weiming Song, 2021. "Thermogravimetric and Kinetic Analysis of High-Temperature Thermal Conversion of Pine Wood Sawdust under CO 2 /Ar," Energies, MDPI, vol. 14(17), pages 1-16, August.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:17:p:5328-:d:623253
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    References listed on IDEAS

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