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Biomass Thermochemical Conversion via Pyrolysis with Integrated CO 2 Capture

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  • Małgorzata Sieradzka

    (AGH University of Science and Technology, Mickiewicza 30 Av., 30-059 Krakow, Poland)

  • Ningbo Gao

    (School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an 710049, China)

  • Cui Quan

    (School of Energy and Power Engineering, Xi’an Jiaotong University, Xi’an 710049, China)

  • Agata Mlonka-Mędrala

    (AGH University of Science and Technology, Mickiewicza 30 Av., 30-059 Krakow, Poland)

  • Aneta Magdziarz

    (AGH University of Science and Technology, Mickiewicza 30 Av., 30-059 Krakow, Poland)

Abstract

The presented work is focused on biomass thermochemical conversion with integrated CO 2 capture. The main aim of this study was the in-depth investigation of the impact of pyrolysis temperature (500, 600 and 700 °C) and CaO sorbent addition on the chemical and physical properties of obtained char and syngas. Under the effect of the pyrolysis temperature, the properties of biomass chars were gradually changed, and this was confirmed by examination using thermal analysis, scanning electron microscopy, X-ray diffraction, and porosimetry methods. The chars were characterised by a noticeable carbon content (two times at 700 °C) resulting in a lower O/C ratio. The calculated combustion indexes indicated the better combustible properties of chars. In addition, structural morphology changes were observed. However, the increasing pyrolysis temperature resulted in changes of solid products; the differences of char properties were not significant in the range of 500 to 700 °C. Syngas was analysed using a gas chromatograph. The following main components were identified: CO, CO 2 , CH 4 , H 2 and C 2 H 4 , C 2 H 6 , C 3 H 6 , C 3 H 8 . A significant impact of CaO on CO 2 adsorption was found. The concentration of CO 2 in syngas decreased with increased temperature, and the highest decrease occurred in the presence of CaO from above 60% to below 30% at 600 °C.

Suggested Citation

  • Małgorzata Sieradzka & Ningbo Gao & Cui Quan & Agata Mlonka-Mędrala & Aneta Magdziarz, 2020. "Biomass Thermochemical Conversion via Pyrolysis with Integrated CO 2 Capture," Energies, MDPI, vol. 13(5), pages 1-18, February.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:5:p:1050-:d:325473
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    12. Śliz, Maciej & Wilk, Małgorzata, 2020. "A comprehensive investigation of hydrothermal carbonization: Energy potential of hydrochar derived from Virginia mallow," Renewable Energy, Elsevier, vol. 156(C), pages 942-950.
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