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Extraction Behaviors of Lignin and Hemicellulose-Derived Sugars During Organosolv Fractionation of Agricultural Residues Using a Bench-Scale Ball Milling Reactor

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  • Tae Hoon Kim

    (R&D Center, SugarEn Co., Ltd., Yongin 16890, Gyeonggi-do, Korea
    Department of Materials Science and Chemical Engineering, Hanyang University, Ansan 15588, Gyeonggi-do, Korea)

  • Hyun Kwak

    (R&D Center, SugarEn Co., Ltd., Yongin 16890, Gyeonggi-do, Korea)

  • Tae Hyun Kim

    (Department of Materials Science and Chemical Engineering, Hanyang University, Ansan 15588, Gyeonggi-do, Korea)

  • Kyeong Keun Oh

    (R&D Center, SugarEn Co., Ltd., Yongin 16890, Gyeonggi-do, Korea
    Department of Chemical Engineering, Dankook University, Youngin 16890, Gyeonggi-do, Korea)

Abstract

Ethanol organosolv fractionation combined with ball milling was conducted on three major agricultural residues: Rice husk (RH), rice straw (RS), and barley straw (BS). The highest lignin extraction yields of RH, RS, and BS were 55.2%, 53.1%, and 59.4% and the purity of lignin recovered was 99.5% for RH and RS, and 96.8% for BS, with similar chemical characteristics, i.e., low molecular weight distributions (1453–1817 g/mol) and poly dispersity index (1.15–1.28). However, considering the simultaneous production of hemicellulose-derived sugars, distinctive fractionation behaviors were shown for the three agricultural residues. The highest hemicellulose-derived sugar yield was 73.8% when RH was fractionated at 170 °C for 30 min. Meanwhile, very low sugar yields of 31.9% and 35.7% were obtained from RS and BS, respectively. The highest glucan-to-glucose conversion yield from enzymatic hydrolysis of fractionated RH reached 85.2%. Meanwhile, the enzymatic digestibility of the fractionated RS and BS was 60.0% and 70.5%, respectively. Consequently, the fractionation efficiency for RH can be improved with fine refinement. For the case of RS, other fractionation process should be applied to achieve effective fractionation performance.

Suggested Citation

  • Tae Hoon Kim & Hyun Kwak & Tae Hyun Kim & Kyeong Keun Oh, 2020. "Extraction Behaviors of Lignin and Hemicellulose-Derived Sugars During Organosolv Fractionation of Agricultural Residues Using a Bench-Scale Ball Milling Reactor," Energies, MDPI, vol. 13(2), pages 1-15, January.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:2:p:352-:d:307384
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    References listed on IDEAS

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    1. Barakat, Abdellatif & Chuetor, Santi & Monlau, Florian & Solhy, Abderrahim & Rouau, Xavier, 2014. "Eco-friendly dry chemo-mechanical pretreatments of lignocellulosic biomass: Impact on energy and yield of the enzymatic hydrolysis," Applied Energy, Elsevier, vol. 113(C), pages 97-105.
    2. Seong Ju Kim & Byung Hwan Um & Dong Joong Im & Jin Hyung Lee & Kyeong Keun Oh, 2018. "Combined Ball Milling and Ethanol Organosolv Pretreatment to Improve the Enzymatic Digestibility of Three Types of Herbaceous Biomass," Energies, MDPI, vol. 11(9), pages 1-10, September.
    3. Shen, Yafei, 2017. "Rice husk silica derived nanomaterials for sustainable applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 453-466.
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