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Development of a Chemical Quasi-Equilibrium Model of Biomass Waste Gasification in a Fluidized-Bed Reactor by Using Aspen Plus

Author

Listed:
  • Vera Marcantonio

    (Department of Agricultural and Forestry Sciences (DAFNE), Tuscia University of Viterbo, Via San Camillo de Lellis, 01100 Viterbo, Italy)

  • Enrico Bocci

    (Department of Nuclear, Subnuclear and Radiation Physics, Marconi University, 00193 Rome, Italy)

  • Danilo Monarca

    (Department of Agricultural and Forestry Sciences (DAFNE), Tuscia University of Viterbo, Via San Camillo de Lellis, 01100 Viterbo, Italy)

Abstract

In the delicate context of climate change, biomass gasification has been demonstrated to be a very useful technology to produce power and hydrogen. Nevertheless, in literature, there is a lack of a flexible and fast but accurate model of biomass gasification that can be used with all the combinations of oxidizing agents, taking into account both organic and inorganic contaminants, and able to give results that are more realistic. In order to do that, a model of biomass gasification has been developed using the chemical engineering software Aspen Plus. The developed model is based on the Gibbs free energy minimization applying the restricted quasi-equilibrium approach via Data-Fit regression from experimental data. The simulation results obtained, considering different mixes of gasifying agents, were compared and validated against experimental data reported in literature for the most advanced fluidized bed technology. The maximum discrepancy value obtained for hydrogen, with respect to experimental data, is of 8%, and all the other values reached by the developed simulations, considering both organic and inorganic compounds, are in good agreement with literature data. The gas yield reached by the developed simulation is in the range of 1.1–1.3 Nm 3 /kg.

Suggested Citation

  • Vera Marcantonio & Enrico Bocci & Danilo Monarca, 2019. "Development of a Chemical Quasi-Equilibrium Model of Biomass Waste Gasification in a Fluidized-Bed Reactor by Using Aspen Plus," Energies, MDPI, vol. 13(1), pages 1-15, December.
    • Handle: RePEc:gam:jeners:v:13:y:2019:i:1:p:53-:d:300293
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    References listed on IDEAS

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    1. Mauro Villarini & Vera Marcantonio & Andrea Colantoni & Enrico Bocci, 2019. "Sensitivity Analysis of Different Parameters on the Performance of a CHP Internal Combustion Engine System Fed by a Biomass Waste Gasifier," Energies, MDPI, vol. 12(4), pages 1-21, February.
    2. Patra, Tapas Kumar & Sheth, Pratik N., 2015. "Biomass gasification models for downdraft gasifier: A state-of-the-art review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 583-593.
    3. Andrea Colantoni & Mauro Villarini & Vera Marcantonio & Francesco Gallucci & Massimo Cecchini, 2019. "Performance Analysis of a Small-Scale ORC Trigeneration System Powered by the Combustion of Olive Pomace," Energies, MDPI, vol. 12(12), pages 1-12, June.
    4. Baruah, Dipal & Baruah, D.C., 2014. "Modeling of biomass gasification: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 806-815.
    5. Ahmed, Tigabwa Y. & Ahmad, Murni M. & Yusup, Suzana & Inayat, Abrar & Khan, Zakir, 2012. "Mathematical and computational approaches for design of biomass gasification for hydrogen production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2304-2315.
    6. Puig-Arnavat, Maria & Bruno, Joan Carles & Coronas, Alberto, 2010. "Review and analysis of biomass gasification models," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(9), pages 2841-2851, December.
    7. Pala, Laxmi Prasad Rao & Wang, Qi & Kolb, Gunther & Hessel, Volker, 2017. "Steam gasification of biomass with subsequent syngas adjustment using shift reaction for syngas production: An Aspen Plus model," Renewable Energy, Elsevier, vol. 101(C), pages 484-492.
    8. N. Florin & A. Harris, 2007. "Hydrogen production from biomass," Environment Systems and Decisions, Springer, vol. 27(1), pages 207-215, March.
    9. Abrar Inayat & Murni M. Ahmad & Suzana Yusup & Mohamed Ibrahim Abdul Mutalib, 2010. "Biomass Steam Gasification with In-Situ CO2 Capture for Enriched Hydrogen Gas Production: A Reaction Kinetics Modelling Approach," Energies, MDPI, vol. 3(8), pages 1-13, August.
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    Cited by:

    1. Vera Marcantonio & Danilo Monarca & Mauro Villarini & Andrea Di Carlo & Luca Del Zotto & Enrico Bocci, 2020. "Biomass Steam Gasification, High-Temperature Gas Cleaning, and SOFC Model: A Parametric Analysis," Energies, MDPI, vol. 13(22), pages 1-13, November.
    2. Lorenzo Bartolucci & Enrico Bocci & Stefano Cordiner & Emanuele De Maina & Francesco Lombardi & Vera Marcantonio & Pietro Mele & Vincenzo Mulone & Davide Sorino, 2023. "Biomass Polygeneration System for the Thermal Conversion of Softwood Waste into Hydrogen and Drop-In Biofuels," Energies, MDPI, vol. 16(3), pages 1-15, January.
    3. María Pilar González-Vázquez & Fernando Rubiera & Covadonga Pevida & Daniel T. Pio & Luís A.C. Tarelho, 2021. "Thermodynamic Analysis of Biomass Gasification Using Aspen Plus: Comparison of Stoichiometric and Non-Stoichiometric Models," Energies, MDPI, vol. 14(1), pages 1-17, January.
    4. Donatella Barisano & Giuseppe Canneto & Francesco Nanna & Antonio Villone & Emanuele Fanelli & Cesare Freda & Massimiliano Grieco & Andrea Lotierzo & Giacinto Cornacchia & Giacobbe Braccio & Vera Marc, 2022. "Investigation of an Intensified Thermo-Chemical Experimental Set-Up for Hydrogen Production from Biomass: Gasification Process Integrated to a Portable Purification System—Part II," Energies, MDPI, vol. 15(13), pages 1-16, June.
    5. Vera Marcantonio & Michael Müller & Enrico Bocci, 2021. "A Review of Hot Gas Cleaning Techniques for Hydrogen Chloride Removal from Biomass-Derived Syngas," Energies, MDPI, vol. 14(20), pages 1-15, October.
    6. Ana Matin & Ivan Brandić & Neven Voća & Nikola Bilandžija & Božidar Matin & Vanja Jurišić & Alan Antonović & Tajana Krička, 2023. "Changes in the Properties of Hazelnut Shells Due to Conduction Drying," Agriculture, MDPI, vol. 13(3), pages 1-15, February.

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