IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v202y2023icp1096-1109.html
   My bibliography  Save this article

Design of a renewable catalyst support derived from biomass with optimized textural features for fischer tropsch synthesis

Author

Listed:
  • Teimouri, Zahra
  • Abatzoglou, Nicolas
  • Dalai, Ajay K.

Abstract

The feasibility of a renewable source for synthesis of mesoporous activated carbon (AC) as catalyst support in Fischer-Tropsch synthesis (FTS) has been investigated. For this purpose, machine learning was used to optimize the process conditions for synthesis of AC (through chemical activation) from biomass. Three different regression methods were carried out to optimize the activation time, temperature, and impregnation ratio. Random forest regression (RFR) resulted in the highest prediction accuracy with R2 of 0.88 and 0.97 for total pore volume (cm3/g) and mesoporosity (%), respectively. The prepared AC at optimum activation conditions (obtained by RFR) led to 90% mesoporosity. Prior to FT reaction, the mineral impurities of the AC were decreased using alkaline treatment. The performances of the Fe catalysts supported on AC (10Fe/AC and 20Fe/AC) were tested for FTS at 300 °C, 2 MPa, and gas hourly space velocity (GHSV) of 2000 h−1. The 20Fe/AC catalyst achieved 46.7% CO conversion and C5+ selectivity of 72.5%, indicating the promising potential of the biomass-based catalyst support with optimized textural features and modified surface for FTS. The 20Fe/AC catalyst showed superior FT activity and C5+ selectivity compared to the 20Fe/Al2O3, and Fe catalyst supported on commercial AC. For 20Fe/AC catalyst, liquid hydrocarbons in the range of C5–C50 were detected.

Suggested Citation

  • Teimouri, Zahra & Abatzoglou, Nicolas & Dalai, Ajay K., 2023. "Design of a renewable catalyst support derived from biomass with optimized textural features for fischer tropsch synthesis," Renewable Energy, Elsevier, vol. 202(C), pages 1096-1109.
    • Handle: RePEc:eee:renene:v:202:y:2023:i:c:p:1096-1109
    DOI: 10.1016/j.renene.2022.11.061
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122017013
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.11.061?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Benedetti, Vittoria & Ail, Snehesh Shivananda & Patuzzi, Francesco & Cristofori, Davide & Rauch, Reinhard & Baratieri, Marco, 2020. "Investigating the feasibility of valorizing residual char from biomass gasification as catalyst support in Fischer-Tropsch synthesis," Renewable Energy, Elsevier, vol. 147(P1), pages 884-894.
    2. Cuéllar-Franca, Rosa & García-Gutiérrez, Pelayo & Dimitriou, Ioanna & Elder, Rachael H. & Allen, Ray W.K. & Azapagic, Adisa, 2019. "Utilising carbon dioxide for transport fuels: The economic and environmental sustainability of different Fischer-Tropsch process designs," Applied Energy, Elsevier, vol. 253(C), pages 1-1.
    3. Jiang, Wen & Xing, Xianjun & Zhang, Xianwen & Mi, Mengxing, 2019. "Prediction of combustion activation energy of NaOH/KOH catalyzed straw pyrolytic carbon based on machine learning," Renewable Energy, Elsevier, vol. 130(C), pages 1216-1225.
    4. Swain, Pravat K. & Das, L.M. & Naik, S.N., 2011. "Biomass to liquid: A prospective challenge to research and development in 21st century," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(9), pages 4917-4933.
    5. Yakaboylu, Gunes A. & Jiang, Changle & Yumak, Tugrul & Zondlo, John W. & Wang, Jingxin & Sabolsky, Edward M., 2021. "Engineered hierarchical porous carbons for supercapacitor applications through chemical pretreatment and activation of biomass precursors," Renewable Energy, Elsevier, vol. 163(C), pages 276-287.
    6. Teimouri, Zahra & Borugadda, Venu Babu & Dalai, Ajay K. & Abatzoglou, Nicolas, 2022. "Application of computational fluid dynamics for modeling of Fischer-Tropsch synthesis as a sustainable energy resource in different reactor configurations: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 160(C).
    7. Garcilaso, V. & Barrientos, J. & Bobadilla, L.F. & Laguna, O.H. & Boutonnet, M. & Centeno, M.A. & Odriozola, J.A., 2019. "Promoting effect of CeO2, ZrO2 and Ce/Zr mixed oxides on Co/γ-Al2O3 catalyst for Fischer-Tropsch synthesis," Renewable Energy, Elsevier, vol. 132(C), pages 1141-1150.
    8. Tang, Zo-Ee & Lim, Steven & Pang, Yean-Ling & Shuit, Siew-Hoong & Ong, Hwai-Chyuan, 2020. "Utilisation of biomass wastes based activated carbon supported heterogeneous acid catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 158(C), pages 91-102.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. David D. J. Antia, 2023. "Conversion of Waste Synthesis Gas to Desalination Catalyst at Ambient Temperatures," Waste, MDPI, vol. 1(2), pages 1-29, May.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Rahimi, Mohammad & Abbaspour-Fard, Mohammad Hossein & Rohani, Abbas, 2021. "A multi-data-driven procedure towards a comprehensive understanding of the activated carbon electrodes performance (using for supercapacitor) employing ANN technique," Renewable Energy, Elsevier, vol. 180(C), pages 980-992.
    2. Douvartzides, Savvas & Charisiou, Nikolaos D. & Wang, Wen & Papadakis, Vagelis G. & Polychronopoulou, Kyriaki & Goula, Maria A., 2022. "Catalytic fast pyrolysis of agricultural residues and dedicated energy crops for the production of high energy density transportation biofuels. Part I: Chemical pathways and bio-oil upgrading," Renewable Energy, Elsevier, vol. 185(C), pages 483-505.
    3. Zhang, Bingxin & Gao, Ming & Tang, Weiqi & Wang, Xiaona & Wu, Chuanfu & Wang, Qunhui & Xie, Haijiao, 2023. "Reduced surface sulphonic acid concentration Alleviates carbon-based solid acid catalysts deactivation in biodiesel production," Energy, Elsevier, vol. 271(C).
    4. Zhao, Xiqiang & Zhou, Xing & Wang, Guoxiu & Zhou, Ping & Wang, Wenlong & Song, Zhanlong, 2022. "Evaluating the effect of torrefaction on the pyrolysis of biomass and the biochar catalytic performance on dry reforming of methane," Renewable Energy, Elsevier, vol. 192(C), pages 313-325.
    5. Gualberto Zavarize, Danilo & Braun, Heder & Diniz de Oliveira, Jorge, 2021. "Methanolysis of low-FFA waste cooking oil with novel carbon-based heterogeneous acid catalyst derived from Amazon açaí berry seeds," Renewable Energy, Elsevier, vol. 171(C), pages 621-634.
    6. Bergthorson, Jeffrey M. & Thomson, Murray J., 2015. "A review of the combustion and emissions properties of advanced transportation biofuels and their impact on existing and future engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1393-1417.
    7. Patuzzi, Francesco & Basso, Daniele & Vakalis, Stergios & Antolini, Daniele & Piazzi, Stefano & Benedetti, Vittoria & Cordioli, Eleonora & Baratieri, Marco, 2021. "State-of-the-art of small-scale biomass gasification systems: An extensive and unique monitoring review," Energy, Elsevier, vol. 223(C).
    8. Neves, Renato Cruz & Klein, Bruno Colling & da Silva, Ricardo Justino & Rezende, Mylene Cristina Alves Ferreira & Funke, Axel & Olivarez-Gómez, Edgardo & Bonomi, Antonio & Maciel-Filho, Rubens, 2020. "A vision on biomass-to-liquids (BTL) thermochemical routes in integrated sugarcane biorefineries for biojet fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    9. Xu, Xiaodong & Sielicki, Krzysztof & Min, Jiakang & Li, Jiaxin & Hao, Chuncheng & Wen, Xin & Chen, Xuecheng & Mijowska, Ewa, 2022. "One-step converting biowaste wolfberry fruits into hierarchical porous carbon and its application for high-performance supercapacitors," Renewable Energy, Elsevier, vol. 185(C), pages 187-195.
    10. Suopajärvi, Hannu & Pongrácz, Eva & Fabritius, Timo, 2013. "The potential of using biomass-based reducing agents in the blast furnace: A review of thermochemical conversion technologies and assessments related to sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 25(C), pages 511-528.
    11. Maity, Sunil K., 2015. "Opportunities, recent trends and challenges of integrated biorefinery: Part II," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1446-1466.
    12. Li, Hui & Wang, Junchi & Ma, Xiaoling & Wang, Yangyang & Li, Guoning & Guo, Min & Cui, Ping & Lu, Wanpeng & Zhou, Shoujun & Yu, Mingzhi, 2021. "Carbonized MIL−100(Fe) used as support for recyclable solid acid synthesis for biodiesel production," Renewable Energy, Elsevier, vol. 179(C), pages 1191-1203.
    13. Janda, Karel & Kourilek, Jakub, 2016. "Description of Biofuels and Shale Gas Development," MPRA Paper 74885, University Library of Munich, Germany.
    14. Chen, Tingting & Luo, Lu & Luo, Lingcong & Deng, Jianping & Wu, Xi & Fan, Mizi & Du, Guanben & Weigang Zhao,, 2021. "High energy density supercapacitors with hierarchical nitrogen-doped porous carbon as active material obtained from bio-waste," Renewable Energy, Elsevier, vol. 175(C), pages 760-769.
    15. Sajjad, H. & Masjuki, H.H. & Varman, M. & Kalam, M.A. & Arbab, M.I. & Imtenan, S. & Rahman, S.M. Ashrafur, 2014. "Engine combustion, performance and emission characteristics of gas to liquid (GTL) fuels and its blends with diesel and bio-diesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 961-986.
    16. Kim, Young-Doo & Yang, Chang-Won & Kim, Beom-Jong & Moon, Ji-Hong & Jeong, Jae-Yong & Jeong, Soo-Hwa & Lee, See-Hoon & Kim, Jae-Ho & Seo, Myung-Won & Lee, Sang-Bong & Kim, Jae-Kon & Lee, Uen-Do, 2016. "Fischer–tropsch diesel production and evaluation as alternative automotive fuel in pilot-scale integrated biomass-to-liquid process," Applied Energy, Elsevier, vol. 180(C), pages 301-312.
    17. Silalertruksa, Thapat & Gheewala, Shabbir H. & Sagisaka, Masayuki & Yamaguchi, Katsunobu, 2013. "Life cycle GHG analysis of rice straw bio-DME production and application in Thailand," Applied Energy, Elsevier, vol. 112(C), pages 560-567.
    18. Qian, Kezhen & Kumar, Ajay & Zhang, Hailin & Bellmer, Danielle & Huhnke, Raymond, 2015. "Recent advances in utilization of biochar," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1055-1064.
    19. Helmi, Fatemeh & Helmi, Maryam & Hemmati, Alireza, 2022. "Phosphomolybdic acid/chitosan as acid solid catalyst using for biodiesel production from pomegranate seed oil via microwave heating system: RSM optimization and kinetic study," Renewable Energy, Elsevier, vol. 189(C), pages 881-898.
    20. Mahrokh Samavati & Andrew Martin & Massimo Santarelli & Vera Nemanova, 2018. "Synthetic Diesel Production as a Form of Renewable Energy Storage," Energies, MDPI, vol. 11(5), pages 1-21, May.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:202:y:2023:i:c:p:1096-1109. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.