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Synergistic effect of sodium content for tuning Sm2O3 as a stable electrolyte in proton ceramic fuel cells

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  • Hu, Enyi
  • Wang, Faze
  • Yousaf, Muhammad
  • Wang, Jun
  • Lund, Peter
  • Wang, Jinping
  • Zhu, Bin

Abstract

Samarium oxide (Sm2O3), a rare earth sesquioxide, shows that a great potential in proton-conducting fuel cells. However, the stability of Sm2O3 based cell remains a challenge. Herein we reported a facile method for enhancing the stability via the incorporation of sodium content into Sm2O3. This study discloses that the existence of sodium induces phase transition of Sm2O3 from monoclinic to cubic phase beneficial for fast proton transportation. Further mechanism investigation reveals that the cubic phase structure of Sm2O3 is stabilized resulting from substitution of sodium. Compared with commercial Sm2O3 (CSM), the fuel cell employing Na–Sm2O3 (NSM) as electrolyte delivers an improved peak power density of 570 mW cm−2 and the extended stability over 100 h under 130 mWcm−2 at 520 °C. In this study, NSM is successfully developed as a stable electrolyte material for proton conduct fuel cells, expanding its application in electrochemical devices.

Suggested Citation

  • Hu, Enyi & Wang, Faze & Yousaf, Muhammad & Wang, Jun & Lund, Peter & Wang, Jinping & Zhu, Bin, 2022. "Synergistic effect of sodium content for tuning Sm2O3 as a stable electrolyte in proton ceramic fuel cells," Renewable Energy, Elsevier, vol. 193(C), pages 608-616.
    • Handle: RePEc:eee:renene:v:193:y:2022:i:c:p:608-616
    DOI: 10.1016/j.renene.2022.04.152
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    1. Chuancheng Duan & Robert J. Kee & Huayang Zhu & Canan Karakaya & Yachao Chen & Sandrine Ricote & Angelique Jarry & Ethan J. Crumlin & David Hook & Robert Braun & Neal P. Sullivan & Ryan O’Hayre, 2018. "Highly durable, coking and sulfur tolerant, fuel-flexible protonic ceramic fuel cells," Nature, Nature, vol. 557(7704), pages 217-222, May.
    2. Chen Xia & Youquan Mi & Baoyuan Wang & Bin Lin & Gang Chen & Bin Zhu, 2019. "Shaping triple-conducting semiconductor BaCo0.4Fe0.4Zr0.1Y0.1O3-δ into an electrolyte for low-temperature solid oxide fuel cells," Nature Communications, Nature, vol. 10(1), pages 1-9, December.
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    1. Shah, M.A.K. Yousaf & Lu, Yuzheng & Mushtaq, Naveed & Yousaf, Muhammad & Akbar, Nabeela & Xia, Chen & Yun, Sining & Zhu, Bin, 2023. "Semiconductor-membrane fuel cell (SMFC) for renewable energy technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 185(C).

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