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Azolla pinnata methyl ester production and process optimization using a novel heterogeneous catalyst

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  • S, Prabakaran
  • T, Mohanraj
  • A, Arumugam

Abstract

This study concentrated on utilizing a novel heterogeneous dolomite catalyst in transesterification of Azolla pinnata algae oil with methanol to convert Azolla pinnata methyl ester (AME). The thermophysical properties of the catalyst were characterized by XRF, XRD, FTIR, and BET analysis. The optimized AME yield of 88.7% was obtained for the methanol to oil molar ratio (30:1), catalyst weight% (4 wt%), and operating temperature of (70 °C) through central composite design (CCD) in response surface methodology (RSM) technique. Five different proportions of Azolla pinnata methyl ester (AME) viz., 10%, 20%, 30%, 40% and 100% by volume were blended with 90%, 80%, 70%, 60% and 0% by volume of diesel. These AME test fuel blends were named AME10, AME20, AME30, AME40, and AME100. American Society for Testing and Materials (ASTM D6751) standards followed to testing the thermophysical properties of prepared biodiesel. AME fuel blends were tested in the single-cylinder variable compression ratio (VCR) engine with varied compression ratios (CR) of 16:1, 17:1, and 18:1 for different loadings at a constant speed of 1500 rpm. The performance, in-cylinder combustion, and exhaust emission results were concluded among five different diesel-AME blends at varied compression ratios. The obtained results for AME blends were compared with the diesel fuel under the same working conditions. At peak load condition, AME30 test fuel with CR18:1 gives a reduction of CO (14.0%), HC (12.06%) and smoke opacity (5.88%) and slight increment in NOx (2.46%) emissions as well as reduced BTE (10.20%) and increased BSEC (17.33%) were obtained related to diesel fuel. Better diffusion phase combustion was recorded for AME blends due to their higher cetane value than neat diesel.

Suggested Citation

  • S, Prabakaran & T, Mohanraj & A, Arumugam, 2021. "Azolla pinnata methyl ester production and process optimization using a novel heterogeneous catalyst," Renewable Energy, Elsevier, vol. 180(C), pages 353-371.
    • Handle: RePEc:eee:renene:v:180:y:2021:i:c:p:353-371
    DOI: 10.1016/j.renene.2021.08.073
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    as
    1. Kumar, Himansh & Sarma, A.K. & Kumar, Pramod, 2020. "A comprehensive review on preparation, characterization, and combustion characteristics of microemulsion based hybrid biofuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 117(C).
    2. Zhen, Xudong & Wang, Yang & Liu, Daming, 2020. "Bio-butanol as a new generation of clean alternative fuel for SI (spark ignition) and CI (compression ignition) engines," Renewable Energy, Elsevier, vol. 147(P1), pages 2494-2521.
    3. Ramalingam, Senthil & Rajendran, Silambarasan & Ganesan, Pranesh & Govindasamy, Mohan, 2018. "Effect of operating parameters and antioxidant additives with biodiesels to improve the performance and reducing the emissions in a compression ignition engine – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 775-788.
    4. Foroutan, Rauf & Mohammadi, Reza & Razeghi, Jafar & Ramavandi, Bahman, 2021. "Biodiesel production from edible oils using algal biochar/CaO/K2CO3 as a heterogeneous and recyclable catalyst," Renewable Energy, Elsevier, vol. 168(C), pages 1207-1216.
    5. Arumugam, A. & Thulasidharan, D. & Jegadeesan, Gautham B., 2018. "Process optimization of biodiesel production from Hevea brasiliensis oil using lipase immobilized on spherical silica aerogel," Renewable Energy, Elsevier, vol. 116(PA), pages 755-761.
    6. Laskar, Ikbal Bahar & Gupta, Rajat & Chatterjee, Sushovan & Vanlalveni, Chhangte & Rokhum, Lalthazuala, 2020. "Taming waste: Waste Mangifera indica peel as a sustainable catalyst for biodiesel production at room temperature," Renewable Energy, Elsevier, vol. 161(C), pages 207-220.
    7. Suresh, M. & Jawahar, C.P. & Richard, Arun, 2018. "A review on biodiesel production, combustion, performance, and emission characteristics of non-edible oils in variable compression ratio diesel engine using biodiesel and its blends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 92(C), pages 38-49.
    8. Kumar, Shiva & Dinesha, P. & Rosen, Marc A., 2019. "Effect of injection pressure on the combustion, performance and emission characteristics of a biodiesel engine with cerium oxide nanoparticle additive," Energy, Elsevier, vol. 185(C), pages 1163-1173.
    9. Nisar, Jan & Razaq, Rameez & Farooq, Muhammad & Iqbal, Munawar & Khan, Rafaqat Ali & Sayed, Murtaza & Shah, Afzal & Rahman, Inayat ur, 2017. "Enhanced biodiesel production from Jatropha oil using calcined waste animal bones as catalyst," Renewable Energy, Elsevier, vol. 101(C), pages 111-119.
    10. Muralidharan, K. & Vasudevan, D., 2011. "Performance, emission and combustion characteristics of a variable compression ratio engine using methyl esters of waste cooking oil and diesel blends," Applied Energy, Elsevier, vol. 88(11), pages 3959-3968.
    11. Sharma, Vikas & Duraisamy, Ganesh & Arumugum, Kanagaraj, 2020. "Impact of bio-mix fuel on performance, emission and combustion characteristics in a single cylinder DICI VCR engine," Renewable Energy, Elsevier, vol. 146(C), pages 111-124.
    12. Vellaiyan, Suresh, 2020. "Enhancement in combustion, performance, and emission characteristics of a biodiesel-fueled diesel engine by using water emulsion and nanoadditive," Renewable Energy, Elsevier, vol. 145(C), pages 2108-2120.
    13. Chamkalani, A. & Zendehboudi, S. & Rezaei, N. & Hawboldt, K., 2020. "A critical review on life cycle analysis of algae biodiesel: current challenges and future prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    14. Arumugam, A. & Sankaranarayanan, Pooja, 2020. "Biodiesel production and parameter optimization: An approach to utilize residual ash from sugarcane leaf, a novel heterogeneous catalyst, from Calophyllum inophyllum oil," Renewable Energy, Elsevier, vol. 153(C), pages 1272-1282.
    15. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.
    16. Hawi, Meshack & Elwardany, Ahmed & Ookawara, Shinichi & Ahmed, Mahmoud, 2019. "Effect of compression ratio on performance, combustion and emissions characteristics of compression ignition engine fueled with jojoba methyl ester," Renewable Energy, Elsevier, vol. 141(C), pages 632-645.
    17. George Anastopoulos & Ypatia Zannikou & Stamoulis Stournas & Stamatis Kalligeros, 2009. "Transesterification of Vegetable Oils with Ethanol and Characterization of the Key Fuel Properties of Ethyl Esters," Energies, MDPI, vol. 2(2), pages 1-15, June.
    18. Muralidharan, K. & Vasudevan, D. & Sheeba, K.N., 2011. "Performance, emission and combustion characteristics of biodiesel fuelled variable compression ratio engine," Energy, Elsevier, vol. 36(8), pages 5385-5393.
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