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Characterization of residues and evaluation of the physico chemical properties of soybean biodiesel and biodiesel: Diesel blends in different storage conditions

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  • Cavalheiro, Leandro Fontoura
  • Misutsu, Marcelo Yukio
  • Rial, Rafael Cardoso
  • Viana, Luíz Henrique
  • Oliveira, Lincoln Carlos Silva

Abstract

In biodiesel, long chain methyl esters crystallize at very low temperatures, forming paraffin crystals that clump together and clog fuel filters, preventing engine operation. When the fuel is at high temperatures and in the presence of oxygen from the air, chemical changes may occur, forming insoluble compounds in the fuel itself. This work followed the evolution of deposits and enhancers formation in biodiesel samples and their mixtures with diesel. Thus, samples of pure biodiesel mixed with diesel were stored under two temperature conditions, 30 °C and 4 °C–10 °C, for a period of 12 months. The results indicate that the residue formation in soybean biodiesel was intensified by the low temperature, time and presence of dissolved water, being the monoglycerides the main inducers.

Suggested Citation

  • Cavalheiro, Leandro Fontoura & Misutsu, Marcelo Yukio & Rial, Rafael Cardoso & Viana, Luíz Henrique & Oliveira, Lincoln Carlos Silva, 2020. "Characterization of residues and evaluation of the physico chemical properties of soybean biodiesel and biodiesel: Diesel blends in different storage conditions," Renewable Energy, Elsevier, vol. 151(C), pages 454-462.
    • Handle: RePEc:eee:renene:v:151:y:2020:i:c:p:454-462
    DOI: 10.1016/j.renene.2019.11.039
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    References listed on IDEAS

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    1. Moser, Bryan R., 2011. "Influence of extended storage on fuel properties of methyl esters prepared from canola, palm, soybean and sunflower oils," Renewable Energy, Elsevier, vol. 36(4), pages 1221-1226.
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    4. Rial, Rafael Cardoso & de Freitas, Osmar Nunes & Santos, Gemima dos & Nazário, Carlos Eduardo Domingues & Viana, Luíz Henrique, 2019. "Evaluation of the oxidative and thermal stability of soybean methyl biodiesel with additions of dichloromethane extract ginger (Zingiber officinale Roscoe)," Renewable Energy, Elsevier, vol. 143(C), pages 295-300.
    5. Dwivedi, Gaurav & Sharma, M.P., 2014. "Impact of cold flow properties of biodiesel on engine performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 650-656.
    6. Shahabuddin, M. & Kalam, M.A. & Masjuki, H.H. & Bhuiya, M.M.K. & Mofijur, M., 2012. "An experimental investigation into biodiesel stability by means of oxidation and property determination," Energy, Elsevier, vol. 44(1), pages 616-622.
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    1. Youssef Kassem & Hüseyin Çamur & Ebaa Alassi, 2020. "Biodiesel Production from Four Residential Waste Frying Oils: Proposing Blends for Improving the Physicochemical Properties of Methyl Biodiesel," Energies, MDPI, vol. 13(16), pages 1-25, August.
    2. Nogueira, Tiago Rocha & de Mesquita Figueredo, Igor & Tavares Luna, Francisco Murilo & Cavalcante, Célio Loureiro & Evangelista de Ávila dos Santos, João & Sousa Lima, Mary Anne & Josino da Silva, Thi, 2020. "Evaluation of oxidative stability of soybean biodiesel using ethanolic and chloroform extracts of Platymiscium floribundum as antioxidant," Renewable Energy, Elsevier, vol. 159(C), pages 767-774.

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