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Clustering and relaxation in oil-continuous microemulsions

Author

Listed:
  • Bedeaux, D.
  • Koper, G.J.M.
  • Smeets, J.

Abstract

In the droplet phase of oil-continuous microemulsions, clustering of the droplets has been observed by a number of experimental techniques such as dielectric constant and viscosity measurements. The clustering is found to be characterized by a droplet radius dependent binding enthalpy. Structure factors obtained using SAXS are found to fit those predicted by Baxter's sticky hard sphere model. An extension of this model to a positive value of the binding enthalpy is given. In dynamic Kerr measurements the slow relaxation due to rotation of clusters is observed.

Suggested Citation

  • Bedeaux, D. & Koper, G.J.M. & Smeets, J., 1993. "Clustering and relaxation in oil-continuous microemulsions," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 194(1), pages 105-113.
    • Handle: RePEc:eee:phsmap:v:194:y:1993:i:1:p:105-113
    DOI: 10.1016/0378-4371(93)90345-5
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    References listed on IDEAS

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    1. Langevin, André & Soumis, François, 1989. "Design of multiple-vehicle delivery tours satisfying time constraints," Transportation Research Part B: Methodological, Elsevier, vol. 23(2), pages 123-138, April.
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    1. Bonet Avalos, J. & Rubí, J.M. & Bedeaux, D. & van der Zwan, G., 1994. "Friction coefficients of axisymmetric particles in suspension," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 211(2), pages 193-217.

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