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Synergistic effect of boron/nitrogen co-doping into graphene and intercalation of carbon black for Pt-BCN-Gr/CB hybrid catalyst on cell performance of polymer electrolyte membrane fuel cell

Author

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  • Lee, W.H.
  • Yang, H.N.
  • Park, K.W.
  • Choi, B.S.
  • Yi, S.C.
  • Kim, W.J.

Abstract

Boron and nitrogen were successfully co-doped into graphene (Gr) nanosheets to which Pt nanoparticles with ∼3.7 nm are uniformly deposited on BCN-Gr. Pt content on BCN-Gr is estimated to be 50 wt.% by TG/DTA analysis. Pt-BCN-Gr is intercalated by different amount of CB (carbon black), and it is designated as Pt-BCN-Gr/CBx (x = 0.0, 0.3, 0.4, 0.5 and 0.6). The membrane electrode assembly is fabricated with commercial Pt-C and Pt-BCN-Gr/CBx as anode and cathode catalysts, respectively. The cell performance is highly consistent with electrochemical active surface area and the best cell performance of 0.54 W/cm2 in power density is achieved for Pt-BCN-Gr/CB0.5. The results show that positive effect of B and N co-doping on cell performance becomes more significant for lower intercalated CB content. Direct comparison between Pt-BCN-Gr/CB and Pt-Gr/CB clearly exhibits that Pt-BCN-Gr/CB shows better cell performance for Pt-BCN-Gr/CB than Pt-Gr/CB at lower CB content. About 28%–157% in cell performance at 0.6 V has been enhanced by B and N co-doping compared with that of Pt-Gr/CB. The enhancement in cell performance and durability is probably attributed to the synergistic effect by B and N co-doping and intercalation by CB.

Suggested Citation

  • Lee, W.H. & Yang, H.N. & Park, K.W. & Choi, B.S. & Yi, S.C. & Kim, W.J., 2016. "Synergistic effect of boron/nitrogen co-doping into graphene and intercalation of carbon black for Pt-BCN-Gr/CB hybrid catalyst on cell performance of polymer electrolyte membrane fuel cell," Energy, Elsevier, vol. 96(C), pages 314-324.
  • Handle: RePEc:eee:energy:v:96:y:2016:i:c:p:314-324
    DOI: 10.1016/j.energy.2015.12.088
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    References listed on IDEAS

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    Cited by:

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    2. Dasari, Bhagya Lakshmi & Nouri, Jamshid M. & Brabazon, Dermot & Naher, Sumsun, 2017. "Graphene and derivatives – Synthesis techniques, properties and their energy applications," Energy, Elsevier, vol. 140(P1), pages 766-778.
    3. Kiyani, Roya & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Nitrogen doped graphene supported palladium-cobalt as a promising catalyst for methanol oxidation reaction: Synthesis, characterization and electrocatalytic performance," Energy, Elsevier, vol. 113(C), pages 1162-1173.
    4. Beltrán-Gastélum, M. & Salazar-Gastélum, M.I. & Flores-Hernández, J.R. & Botte, G.G. & Pérez-Sicairos, S. & Romero-Castañon, T. & Reynoso-Soto, E. & Félix-Navarro, R.M., 2019. "Pt-Au nanoparticles on graphene for oxygen reduction reaction: Stability and performance on proton exchange membrane fuel cell," Energy, Elsevier, vol. 181(C), pages 1225-1234.
    5. Ji, Zhaoqi & Perez-Page, Maria & Chen, Jianuo & Rodriguez, Romeo Gonzalez & Cai, Rongsheng & Haigh, Sarah J. & Holmes, Stuart M., 2021. "A structured catalyst support combining electrochemically exfoliated graphene oxide and carbon black for enhanced performance and durability in low-temperature hydrogen fuel cells," Energy, Elsevier, vol. 226(C).

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